355833-53-3Relevant academic research and scientific papers
Dual Functional Half-Sandwich Ru(II) Complexes: Lysosome-Targeting Probes and Anticancer Agents
Liu, Zhe,Li, JuanJuan,Kong, Deliang,Tian, Meng,Zhao, Yao,Xu, Zhishan,Gao, Wenyuan,Zhou, Yumin
, p. 287 - 294 (2019/01/10)
It is known that the proposed biologically active form of ruthenium is its oxidation state II other than oxidation state III, and ruthenium complexes offer the potential of a novel mechanism of action, reduced toxicity. Herein, three half-sandwich Ru
Electrophilic RhI catalysts for arene H/D exchange in acidic media: Evidence for an electrophilic aromatic substitution mechanism
Webster-Gardiner, Michael S.,Piszel, Paige E.,Fu, Ross,McKeown, Bradley A.,Nielsen, Robert J.,Goddard, William A.,Gunnoe, T. Brent
, p. 381 - 388 (2016/12/16)
A series of new rhodium (I) complexes supported by bidentate nitrogen-donor ligands with varying electronic and steric properties were synthesized in situ and evaluated for catalytic arene C–H/D activation. In trifluoroacetic acid (HTFA), these complexes are proposed to mediate H/D exchange of arene C–H/D bonds by an electrophilic aromatic substitution mechanism that involves Rh-mediated activation of HTFA (or DTFA). DFT calculations support the proposed pathway for the H/D exchange reactions.
Highly active and cis-1,4 selective polymerization of 1,3-butadiene catalyzed by cobalt(II) complexes bearing α-diimine ligands
Jia, Xiangyu,Liu, Heng,Hu, Yanming,Dai, Quanquan,Bi, Jifu,Bai, Chenxi,Zhang, Xuequan
, p. 1560 - 1569 (2013/10/01)
A series of cobalt(II) complexes bearing α-diimine ligands were synthesized and characterized by elemental and spectroscopic analysis. These complexes had the general formulas [ArN=C(Me)-(Me)C=NAr]CoCl2 (Ar = C6H5, 3a; 4-M
Dialkyl aluminium amides: New reagents for the conversion of C=O into C=NR functionalities
Gordon, John C.,Shukla, Piyush,Cowley, Alan H.,Jones, Jamie N.,Webster Keogh,Scott, Brian L.
, p. 2710 - 2711 (2007/10/03)
A new methodology for the preparation of α-diimines and β-aminoenones has been devised and represents an alternative route to these and related nitrogenous ligands bearing highly electronegative substituents.
