35584-80-6Relevant articles and documents
Reactions of organocobaloximes with aryldisulfonyl chlorides
Gupta,Vijaikanth
, p. 1102 - 1109 (2004)
Photochemical reactions of benzyl, heteroaromaticmethyl and allylcobaloximes with aryldisulfonyl chlorides yield symmetrical disulfones. Allyl cobaloximes yield allyldisulfones as the major product whereas bibenzyl is the major product in benzylcobaloximes. A time dependent 1H NMR studies show that bibenzyl is formed from O -benzyldimethylglyoxime - a predominant product in the initial stage of the reaction.
Generation and Trapping of Benzyl Radicals from Benzyl Iodides by Cobaloxime-mediated Iodine Atom Abstractions
Brown, Trevor M.,Cooksey, Christopher J.,Crich, David,Dronsfield, Alan T.,Ellis, Robert
, p. 2131 - 2136 (2007/10/02)
Ethylcobaloxime has been demonstrated to function as a convenient source of ethyl radicals on white light photolysis in ethanol.The ethyl radicals so generated take part in iodine abstractions with benzyl iodides giving benzyl radicals which may be trapped with 2,2,6,6-tetramethylpiperidinyloxyl (TEMPO) or lepidinium camphor-10-sulfonate.
HOMOLYTIC DISPLACEMENT AT SATURATED CARBON CENTRE: SYNTHESIS OF BENZYLSULPHONES
Gupta, B. D.,Kumar, Manoj,Das, Indira,Roy, M.
, p. 5773 - 5776 (2007/10/02)
The reactions of benzyl cobaloximes with p-substitued benzene sulphonyl chlorides under photochemical conditions from benzyl sulphones by novel SH2 process.
