35599-21-4Relevant academic research and scientific papers
Mitsunobu-like Processes with a Novel Triphenylphosphine-Cyclic Sulfamide Betaine
Castro, Jose L.,Matassa, Victor G.,Ball, Richard G.
, p. 2289 - 2291 (1994)
An unprecedented adduct 10 between triphenylphosphine (TPP) and 3,3-dimethyl-1,2,5-thiadiazolidine 1,1-dioxide (8) is described, which can be regarded as a stable source of the (1+) species, and was utilized to efficiently promote the coupling betwe
Efficacious modification of the Mitsunobu reaction for inversions of sterically hindered secondary alcohols
Martin,Dodge
, p. 3017 - 3020 (2007/10/02)
A practical modification of the Mitsunobu protocol for effecting stereochemical inversions of alcohols has been discovered in which use of p-nitrobenzoic acid as the nucleophilic partner results in significantly improved yields with relatively hindered su
