35646-82-3

Basic information

• Product Name: (CO)5MnCo(CO)4
• Synonyms: (CO)5MnCo(CO)4
• CAS NO: 35646-82-3
• Molecular Weight: 366.025
• Mol File: 35646-82-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (CO)5MnCo(CO)4(CAS DataBase Reference)
• NIST Chemistry Reference: (CO)5MnCo(CO)4(35646-82-3)
• EPA Substance Registry System: (CO)5MnCo(CO)4(35646-82-3)

Safety Data

• Hazardous Substances Data: 35646-82-3(Hazardous Substances Data)

Upstream product

• 16972-33-1 pentacarbonylhydridomanganese 
• 64519-62-6 cobalt tetracarbonyl hydride 
• 15226-74-1 dicobalt octacarbonyl 
• 96255-23-1 pentacarbonyl(methylsilyl)manganese 
• 28300-66-5 (ethoxycarbonyl)manganese pentacarbonyl 

Downstream Products

• 237056-17-6 MnCo(CO)8(CNC₆H₄-p-OMe) 
• 237056-10-9 MnCo(CO)7(CN-2,6-xylyl)2 
• 237056-09-6 MnCo(CO)8(CN-2,6-xylyl) 
• 10170-69-1 dimanganese decacarbonyl 
• 84685-75-6 Co₂(CO)6(C₄H₉CP)W(CO)5 

Relevant articles and documents

Kinetic investigation of the mixed-metal bimolecular reductive eliminations in the reactions of EtOC(O)CH2M(CO)n or EtOC(O)M(CO)n (M = Co, n = 4; M = Mn, n = 5) with HCo(CO)4 or HMn(CO)5

The alkyl- and acylmetal carbonyls EtOC(O)CH2M(CO)n and EtOC(O)M(CO)n (M = Co, n = 4; M = Mn, n = 5) react with HCo(CO)4 or HMn(CO)5 to yield ethyl acetate or ethyl formate and the corresponding binuclear metal carbonyl. Kinetic experiments support a mechanism according to which the reaction between a coordinatively unsaturated alkyl- or acylmetal carbonyl (formed by CO loss) and the metal carbonyl hydride is rate determining. The rate of this bimolecular reductive elimination step varies strongly and unexpectedly in the mixed-metal systems.