84685-75-6Relevant academic research and scientific papers
SYNTHESES OF MIXED TRANSITION METAL CLUSTERS CONTAINING THE COORDINATED PHOSPHAALKYNE tBuCP
Bartsch, Rainer,Nixon, John F.,Sarjudeen, Nigel
, p. 267 - 272 (1985)
Syntheses of the phosphaalkyne complexes 5-C5H5)2(tBuCP)> and 5-C5H5)(CO)3(tBuCP)> are described.Adducts of the latter with and 5-C5H5)> are also reported.The reactions
NOVEL TRANSITION METAL PHOSPHA-ALKYNE COMPLEXES: tBuCP ACTING AS A 6 ELECTRON DONOR LIGAND. SYNTHESIS, CRYSTAL AND MOLECULAR STRUCTURE OF tBuCP)W(CO)5>
Burckett-St Laurent, James C.T.,Hitchcock, Peter B.,Kroto, Harold W.,Meidine, Mohammed, F.,Nixon, John F.
, p. C82 - C84 (1982)
A single crystal X-ray diffraction study of tBuCP)W(CO)5> establishes that phospha-alkyne behaves as a 6e donor.Synthesis of the related 5-C5H5)2Mo2(CO)4(μ-tBuCP)W(CO)5> complex is reported.
