356552-15-3Relevant academic research and scientific papers
Catalytic Formal Benzylic C-H Bond Functionalization of 2,5-Dialkylfuran Derivatives with Ferrocenyl Alcohols as Alkylation Reagents
Ren, Didi,Xu, Lubin,Wang, Liang,Li, Shuai-Shuai
supporting information, p. 627 - 631 (2019/02/12)
The inert benzylic C-H bond of π-electron-rich heteroaromatic 2,5-dialkylfuran derivatives was conveniently functionalized with ferrocenyl alcohols as alkylation reagents under catalytic acidic conditions at room temperature, which features chemo- and reg
Cobalt-Catalyzed Oxygenation/Dearomatization of Furans
Oswald, Jonathan P.,Woerpel
, p. 9067 - 9075 (2018/05/29)
The dearomatization of aromatic compounds using cobalt(II) acetylacetonate with triplet oxygen and triethylsilane converts furans, benzofurans, pyrroles, and thiophenes to a variety of products, including lactones, silyl peroxides, and ketones.
Gold catalysis: Non-spirocyclic intermediates in the conversion of furanynes by the formal insertion of an alkyne into an aryl-alkyl C-C single bond
Hashmi, A. Stephen K.,Haeffner, Tobias,Yang, Weibo,Pankajakshan, Sreekumar,Schaefer, Sascha,Schultes, Lara,Rominger, Frank,Frey, Wolfgang
supporting information, p. 10480 - 10486 (2012/11/07)
It takes al-kynes: The formation of furyl-substituted heterocycles from furanynes with donor groups on the furan-alkyne tether and mechanistic control experiments indicate the involvement of open-chained carbenium ions in the overall insertion of an alkyne into a C-C bond, rather than the usual spirocyclic intermediates (see scheme). Copyright
An easy access to unsymmetric trisubstituted methane derivatives (TRSMs)
Kumar Das, Sajal,Shagufta,Panda, Gautam
, p. 3097 - 3102 (2007/10/03)
A new series of unsymmetric trisubstituted methane derivatives (TRSMs) has been synthesized through Friedel-Crafts alkylation of aromatic nucleophiles using acid-sensitive heteroaryl carbinols.
