35657-10-4Relevant academic research and scientific papers
2-Sulfinyl Oxetanes: Synthesis, Stability and Reactivity
Morgan, Kate F.,Doran, Robert,Croft, Rosemary A.,Hollingsworth, Ian A.,Bull, James A.
, p. 106 - 110 (2016)
The synthesis of 2-sulfinyl oxetanes is described by a C-C bond-forming cyclisation strategy. Oxetanes bearing electron-poor aryl sulfoxides are shown to be viable targets using this strategy. We report investigations into the sulfoxide magnesium exchange
Relative Reactivities of Various Sulfides, Selenides and Halides Towards SH2 Attack by Tributyltin Radicals
Beckwith, Athelstan L. J.,Pigou, Paul E.
, p. 77 - 87 (2007/10/02)
The order of reactivity towards SH2 attack by tributyltin radicals on various groups X in four different molecular environments (RCO2CH2X, RCH2OCH2X, XCH2CO2Et and RCH2X) has been found by competition experiments to be Br > PhSe > Cl > p-CNC6H4S > PhS > p-MeC6H4S > MeS.The mechanism of the reaction of chloromethyl phenyl sulfide with alkoxides is discussed.
