356760-74-2

Upstream product

• 67-56-1 methanol 
• 105539-79-5 1(R)-4-exo-(benzoyloxy)-1-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-6-oxabicyclo<3.2.1>oct-2-en-7-one 

Downstream Products

• 639806-91-0 (1R,3R,4R)-1-(tert-butyldimethylsilyloxy)-4-(2'-nitrobenzyloxy)cyclohex-5-en-1,3-carbolactone 
• 639806-90-9 (1R,3R,4R)-1-(tert-butyldimethylsilyloxy)-4-(4'-nitrobenzyloxy)cyclohex-5-en-1,3-carbolactone 
• 356760-75-3 (1R,4R,5R)-4-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-6-oxa-bicyclo[3.2.1]oct-2-en-7-one 
• 504397-89-1 (1S,2R,3R,4S,5R)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-cyclohexane-1,2,3,4,5-pentaol 
• 504397-87-9 (1R,2S,3S,4S,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxymethyl-cyclohexane-1,2,3,4-tetraol 
• 504397-88-0 (1R,2S,3R,4R,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxymethyl-cyclohexane-1,2,3,4-tetraol 
• 40983-52-6 (1R,2S,3S,4S,5R)-1,2,3,4,5-pentahydroxycyclohexane-1-carboxylic acid 
• 639806-93-2 (1R,3R,4R)-1-hydroxy-4-(2'-nitrobenzyloxy)cyclohex-5-en-1,3-carbolactone 
• 639806-92-1 (1R,3R,4R)-1-hydroxy-4-(4'-nitrobenzyloxy)cyclohex-5-en-1,3-carbolactone 

Relevant academic research and scientific papers

Synthesis of polyhydroxycyclohexanes and relatives from (-)-quinic acid

An efficient and versatile strategy for the synthesis of polyhydroxycyclohexanes and related compounds 3-6 is reported. The successful synthesis of these analogues has been achieved from a common intermediate, quinic acid derived lactone 2, rapidly access

Synthesis of carba-sugars from (-)-quinic acid

(1S,2R,3R,4S,5R)- (3a) and (1S,2S,3S,4S,5R)-1,2,3,4,5-pentahydroxy-1-hydroxymethylcyclohexane (4a), (1R,2R,3R,4S,5R)- (3b) and (1R,2S,3S,4S,5R)-1,2,3,4,5-pentahydroxycyclohexan-1-carboxylic acid (4b) are reported. The syntheses exploit the diastereoselective oxidation of the 5,6-double bond of the quinic acid-derived lactone 2 with osmium tetroxide.