35684-38-9

Upstream product

• 103-73-1 Phenetole 
• 36310-31-3 p-ethoxyphenyltellurium(IV) trichloride 
• 104781-72-8 5-{[(4-ethoxy-phenyl)-diiodo-λ⁴-tellanyl]-methyl}-3,3-diphenyl-dihydro-furan-2-one 
• 102936-12-9 Acetonyl-(4-ethoxy-phenyl)-tellurdichlorid 
• 119030-15-8 {PdCl₂(Te₂(C₆H₄OCH₂CH₃-4)2)}2 
• 117075-32-8 PtCl₂(Te₂(C₆H₄OEt-4)2)2 
• 7732-18-5 water 
• 182947-20-2 2,2,2-trifluoro-1-(3-phenylbicyclo[2.2.1]hepta-2,5-dien-2-yl)ethan-1-one 
• 109042-38-8 (4-Ethoxy-phenyl)-(2,4-dihydroxy-phenyl)-tellurdichlorid 
• 67096-36-0 Phenacyl-<4-aethoxy-phenyl>-tellurdichlorid 
• 122182-99-4 C₁₃H₁₆Cl₂O₃Te 

Downstream Products

• 29372-64-3 o-Phenylen-bis- 
• 67264-18-0 Mercury(II); 4-ethoxy-benzenetellurolate 
• 36310-31-3 p-ethoxyphenyltellurium(IV) trichloride 
• 77443-59-5 C₁₄H₁₄ClNO₃STe 
• 77443-58-4 C₁₄H₁₄BrNO₃STe 
• 92588-87-9 bis(p-ethoxyphenyl)ditelluride * 2 (7,7,8,8-tetracyano-p-quinodimethane) 
• 77443-61-9 C₈H₉ClOTe 
• 77955-72-7 C₈H₉IOTe 
• 562835-50-1 (Z)-3-(4-Ethoxy-phenyltellanyl)-prop-2-en-1-ol 
• 107840-20-0 1,2-bis-(4-ethoxyphenyltelluromethyl)benzene 
• 56950-07-3 1-Ethoxy-4-phenylethynyltellanyl-benzene 

Relevant academic research and scientific papers

Mild reduction of tellurium(IV) and selenium(IV) compounds by sodium ascorbate

Sodium ascorbate was found to mildly reduce organyltellurium trihalides to diorganyl ditellurides, organylselenium trihalides to diorganyl diselenides, diorganyltellurium dihalides and oxides to diorganyl tellurides and diorganylselenium dihalides and oxides to diorganyl selenides.

REACTIONS OF ACETYLACETONE WITH ORGANOTELLURIUM (IV) CHLORIDES-C1 BONDED ACETYLACETONATES OF TELLURIUM(IV)

The reactions of acetylacetone (AcAc) with ArTeCl3 (I), Ar2TeCl2 (II) and Ar3TeCl (III) (where Ar = phenyl, 4-hydroxyphenyl, 4-methoxyphenyl, 4-ethoxyphenyl, 3-methyl-4-hydroxyphenyl and 3,4-dihydroxyphenyl) have been investigated.The I gives ArTe(C5H7O2)Cl2 (IV) type derivatives but II and III do not react even on prolonged refluxing in the presence of anhydrous AlCl3.The structural features of the new acetonylacetone derivatives (IV) have been explored by IR, PMR, and CMR spectroscopy.The effect of phenyl ring substituents on the keto-enol tautomerism of IVhas been found to be minor.The bond formation between Te and C1 of AcAc and intramolecular secondary interaction between the oxygen of AcAc and Te have been inferred from spectral data.

REACTIONS OF TELLURIUM(IV) CHLORIDES WITH SOME ORGANOSILICON HYDRIDES

The reactions of several organosilicon hydrides PhnSiH(4-n), n = 1, 2; R3SiH, R3 = Ph3, Ph2Me, PhMe2, (n-C6H13)3; (p-Me2HSi)2C6H4, with TeCl4 in benzene resulted in the formation of tellurium metal and chlorosilanes in 75-90percent yields.Similar reactions with aryltellurium trichlorides (RTeCl3, R = Ph, p-MeOC6H4, p-EtOC6H4) proceeded in two different ways.On stirring at room temperature for 6-8 h, diaryl ditellurides and chlorosilanes were obtained in 70-95percent yields whereas on refluxing for 6-10 h, tellurium powder and diaryltellurium dichlorides were obtained along withthe chlorosilanes in 80-95percent yields.Diaryltellurium dichlorides (R2TeCl2, R = Ph, p-MeOC6H4) did not react readily with PhSiH3 nor with Ph3SiH.