357194-31-1

Basic information

• Product Name: (+/-)-(5-benzyl-2,5-dimethyl-cyclohexenyloxy)trimethylsilane
• Synonyms: (+/-)-(5-benzyl-2,5-dimethyl-cyclohexenyloxy)trimethylsilane
• CAS NO: 357194-31-1
• Molecular Weight: 288.505
• Mol File: 357194-31-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+/-)-(5-benzyl-2,5-dimethyl-cyclohexenyloxy)trimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: (+/-)-(5-benzyl-2,5-dimethyl-cyclohexenyloxy)trimethylsilane(357194-31-1)
• EPA Substance Registry System: (+/-)-(5-benzyl-2,5-dimethyl-cyclohexenyloxy)trimethylsilane(357194-31-1)

Safety Data

• Hazardous Substances Data: 357194-31-1(Hazardous Substances Data)

Upstream product

• 1193-18-6 3-methylcyclohexen-2-one 
• 15329-10-9 3,6-dimethylcyclohex-2-enone 
• 75-77-4 chloro-trimethyl-silane 

Relevant articles and documents

Tri- and tetrasubstituted α-fluorocyclohexanones with enantiomeric excesses in the range of 97-100%

The α-fluorinated trisubstituted ketones (2S,5R)-(-)-7-Ia, (2R,5R)-(+)-7-IIe, (2S,5R)-(-)-8-Ia and (2R,5R)-(+)-8-IIe were synthesised from (+)-dihydrocarvone (99% (R)-configuration at C-5) and fully characterised. α-Fluorinated tetrasubstituted ketones (-)-9-Ia, (+)-9-Ia, (+)-9-IIa and (+)-10-Ia having e.e.s of ≥97% were synthesised as racemates from 3-methyl cyclo-hexenone then resolved into the pure enantiomers using chiral HPLC and fully characterised.