357400-98-7

Upstream product

• 87-72-9 D-Xylose 
• 100-52-7 benzaldehyde 
• 357400-94-3 methyl 2,4-anhydro-5-O-benzyl-D-lyxonate 
• 15384-37-9 D-xylono-1,4-lactone 
• 131614-83-0 (2S,4aR,7R,7aR)-7-hydroxy-2-phenyltetrahydro-6H-furo[3,2-d][1,3]dioxin-6-one 
• 131550-06-6 methyl 2,4-anhydro-(S)-3,5-benzylidene-D-lyxonate 
• 130481-72-0 (S)-3,5-O-benzylidene-2-O-trifluoromethanesulfonyl-D-xylono-1,4-lactone 
• 357400-97-6 methyl 2,4-anhydro-5-O-benzyl-3-O-trifluoromethanesulfonyl-D-lyxonate 

Relevant academic research and scientific papers

Oxetane cis- and trans β-amino-acid scaffolds from d-xylose by efficient SN2 reactions in oxetane rings: Methyl and hydroxymethyl analogues of the antibiotic oxetin, an oxetane β-amino-acid

Highly regioselective reactions of a benzylidene-protected oxetane with (i) triethylsilane-trifluoroacetic acid and (ii) Hanessian-Hullar bromination provide efficient access to 3-hydroxyoxetane carboxylates in which only the C-3 OH is unprotected. Subseq

cis- and trans-3-Azido-oxetane-2-carboxylate scaffolds: Hexamers of oxetane cis-β-amino acids

Efficient synthesis of both cis- and trans-3-azido-oxetane-2-carboxylates relies upon efficient nucleophilic displacements of 3-O-triflates of oxetanes by trifluoroacetate and azide. Such structures are scaffolds for incorporation of oxetane-β-amino acids into oligomers; the synthesis of a series of protected β-hexapeptides and the X-ray crystal structure of methyl 2,4-anhydro-6-deoxy-5-O-benzyl-L-altronate are reported.