357407-84-2Relevant academic research and scientific papers
Toward the creation of NMR databases in chiral solvents for assignments of relative and absolute stereochemistry: proof of concept.
Kobayashi,Hayashi,Tan,Kishi
, p. 2245 - 2248 (2007/10/03)
[structure: see text] An NMR database approach in a chiral solvent allows us to predict both relative and absolute stereochemistry of an unknown compound without degradation and/or derivatization. N,alpha-Dimethylbenzylamine (DMBA) is a suitable solvent for this purpose. Using the C.5-C.10 portion of oasomycin A, the feasibility and reliability of this approach is demonstrated.
