357418-50-9

Basic information

• Product Name: 3-Cyclohexene-1-carboxylicacid,1-methyl-,methylester,(1R)-(9CI)
• Synonyms: 3-Cyclohexene-1-carboxylicacid,1-methyl-,methylester,(1R)-(9CI)
• CAS NO: 357418-50-9
• Molecular Formula: C9H14O2
• Molecular Weight: 154.21
• Product Categories: CARBOXYLICESTER
• Mol File: 357418-50-9.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-Cyclohexene-1-carboxylicacid,1-methyl-,methylester,(1R)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Cyclohexene-1-carboxylicacid,1-methyl-,methylester,(1R)-(9CI)(357418-50-9)
• EPA Substance Registry System: 3-Cyclohexene-1-carboxylicacid,1-methyl-,methylester,(1R)-(9CI)(357418-50-9)

Safety Data

• Hazardous Substances Data: 357418-50-9(Hazardous Substances Data)

Upstream product

• 6493-77-2 methyl cyclohex-3-ene-1-carboxylate 
• 74-88-4 methyl iodide 
• 106-99-0 buta-1,3-diene 
• 80-62-6 methacrylic acid methyl ester 
• 135616-40-9 (R,R)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine 
• 147396-58-5 buta-2,3-dien-1-yl 4-methylbenzenesulfonate 
• 135616-36-3 6,6'-((1E,1'E)-((1S,2S)-cyclohexane-1,2-diylbis(azanylylidene)) bis(methanylylidene))bis(2,4-di-tert-butylphenol) 

Downstream Products

• 85319-23-9 3-(2-Methanesulfonyl-acetyl)-3-methyl-cyclohexanone 
• 344332-94-1 1-(3-Hydroxy-1-methyl-cyclohexyl)-2-methanesulfonyl-ethanone 
• 699-42-3 1-methyl-2,4-cyclohexadienecarbonsaeure-methylester 
• 76657-91-5 trans-1-Hydroxy-4-methyl-4-cyclohexancarbonsaeure 
• 87787-02-8 (1α,4β)-1-methyl-4-hydroxycyclohexanecarboxylic acid methyl ester 

Relevant articles and documents

New entry to the enantioselective formation of substituted cyclohexenes bearing an all-carbon quaternary stereogenic center

Enantioselective formation of cyclohexene derivatives bearing an all-carbon quaternary stereogenic center is described. The racemic cyclohexenes are readily transformed to chiral substituted cyclohexenes in good yield with excellent enantioselectivity and diastereoselectivity by a palladium-mediated deracemization. The resulting products are promising synthetic intermediates of biologically active natural products. This protocol provides us with a new entry to the concise and scalable synthesis of multifunctionalized compounds.

Enantioselective Diels-Alder reactions of optically active (buta-1,3-dien-2-yl)(salen)cobalt(iii) complexes

The syntheses of two optically active (buta-1,3-dien-2-yl)(salen)Co complexes are reported. These dienyl complexes undergo Diels-Alder reactions with high enantioselectivity with a variety of dienophiles. One of the (salen)Co-substituted Diels-Alder cyclo

Enones with Strained Double Bonds. 8. The Bicyclooctane Systems

The bicyclic enones bicyclooct-1-en-3-one (4) and 1-methylbicyclooct-5(6)-en-7-one (5) have been generated from various precursors and trapped by the addition of nucleophiles such as MeOH, PhSeH, or H2O.The bridgehead enone 5 has also been trapped as its cycloadduct 31 with furan.Pyrolysis of this cycloadduct 31 reformed the bridgehead enone 5 that was trapped as the cycloadduct 32.Related bridgehead enones 35 and 47 have also been generated as intermediates leading to products with bridgehead methoxy substituents.