357439-38-4

Upstream product

• 244770-75-0 (2S,3S,4R,4aS,9aS)-4-Benzyloxy-2-iodomethyl-3-(4-methoxy-benzyloxy)-3,4,4a,6,9,9a-hexahydro-2H-1,5-dioxa-benzocycloheptene 
• 776315-69-6 2-bromo-1-(2,2-dimethyl-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-3-yl)-ethanone 
• 136030-00-7 (1R,2S)-1-Amino-2-indanol 
• 357439-31-7 1-((3aR,8aS)-2,2-Dimethyl-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-3-yl)-2-[(2R,4S,5R)-2-(4-methoxy-phenyl)-4-vinyl-[1,3]dioxan-5-yloxy]-ethanone 

Downstream Products

• 357439-45-3 11-benzyloxy-3-[2-(tert-butyl-diphenyl-silanyloxy)-1-(tert-butyl-diphenyl-silanyloxymethyl)-but-3-enyloxy]-2-methoxy-2-vinyl-2,3,4,4a,5a,6,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalene 
• 676609-78-2 C₂₄H₃₀O₇ 
• 776315-71-0 C₇₆H₈₉NO₁₀Si₂ 
• 776315-72-1 C₆₈H₈₁NO₉Si₂ 
• 357439-44-2 (3S,4aR,5aS,10aS,11R,11aR)-11-Benzyloxy-3-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxy)-1-(tert-butyl-diphenyl-silanyloxymethyl)-but-3-enyloxy]-2-vinyl-2,3,4,4a,5a,6,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-2-ol 
• 357439-47-5 (2R,3S,4aR,5aS,10aS,11R,11aR)-11-Benzyloxy-3-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxy)-1-(tert-butyl-diphenyl-silanyloxymethyl)-but-3-enyloxy]-2-vinyl-2,3,4,4a,5a,6,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalene 
• 357439-43-1 (3S,4aR,5aS,10aS,11R,11aR)-11-Benzyloxy-3-[(1R,2S)-2-(tert-butyl-diphenyl-silanyloxy)-1-(tert-butyl-diphenyl-silanyloxymethyl)-but-3-enyloxy]-4,4a,5a,6,9,10a,11,11a-octahydro-3H-1,5,10-trioxa-cyclohepta[b]naphthalen-2-one 
• 357439-48-6 Acetic acid (S)-1-[(R)-2-acetoxy-1-((2R,3S,4aR,5aS,10aS,11R,11aR)-11-benzyloxy-2-vinyl-2,3,4,4a,5a,6,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-3-yloxy)-ethyl]-allyl ester 
• 776315-73-2 (2R,3S)-2-((2R,3S,4aR,5aS,10aS,11R,11aR)-11-Benzyloxy-2-vinyl-2,3,4,4a,5a,6,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-3-yloxy)-pent-4-ene-1,3-diol 
• 776315-99-2 C₄₅H₄₉NO₉S 
• 776316-00-8 C₄₅H₄₉NO₉S 
• 776316-01-9 C₄₅H₄₉NO₁₀ 
• 776315-86-7 C₄₆H₅₈O₉SSi 
• 776315-97-0 C₄₂H₄₅NO₈S 

Relevant academic research and scientific papers

Stereocontrolled synthesis of the ABCDE ring moiety of ciguatoxin CTX3C

The ABCDE ring moiety of ciguatoxin CTX3C, a major causative agent of ciguatera poisoning, was stereoselectively synthesized. The key transformations are a chiral auxiliary-based asymmetric alkylation and an asymmetric aldol condensation, which controlled

Highly stereocontrolled synthesis of the ABCD ring fragment of ciguatoxin CTX3C

A combination of asymmetric alkylation using (1R,2S)-1-amino-2-indanol derivative as a chiral auxiliary and the ring-closing metathesis reaction was shown to be an efficient method for synthesizing the ABCD ring fragment of ciguatoxin CTX3C.