35754-82-6

Basic information

• Product Name: MAGNESIUM N-PROPOXIDE
• Synonyms: MAGNESIUM DI-N-PROPOXIDE;MAGNESIUM N-PROPOXIDE;magnesium dipropanolate;Dipropoxymagnesium;Magnesium di(1-propanolate);Magnesium dipropoxide
• CAS NO: 35754-82-6
• Molecular Formula: 2C₃H₇O*Mg
• Molecular Weight: 142.48
• EINECS: 252-712-8
• Mol File: 35754-82-6.mol
• Article Data: 12

Chemical Properties

• Melting Point: >100°C
• Boiling Point: 95.8°Cat760mmHg
• Flash Point: >65°C
• Appearance: /
• Density: g/cm³
• Vapor Pressure: 26.3mmHg at 25°C
• CAS DataBase Reference: MAGNESIUM N-PROPOXIDE(CAS DataBase Reference)
• NIST Chemistry Reference: MAGNESIUM N-PROPOXIDE(35754-82-6)
• EPA Substance Registry System: MAGNESIUM N-PROPOXIDE(35754-82-6)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• TSCA: No
• Hazardous Substances Data: 35754-82-6(Hazardous Substances Data)

Usage

InChI:InChI=1/2C3H7O.Mg/c2*1-2-3-4;/h2*2-3H2,1H3;/q2*-1;+2

Upstream product

• 71-23-8 propan-1-ol 
• 113353-82-5 Mg⁽¹⁺⁾*C₂H₅OH=Mg(C₂H₅OH)⁽¹⁺⁾ 
• 15921-15-0 Mg⁽¹⁺⁾(n-BuOH) 
• 113353-83-6 Mg⁽¹⁺⁾*CH₃CHO=Mg(CH₃CHO)⁽¹⁺⁾ 
• 113353-85-8 Mg⁽¹⁺⁾*C₂H₅CHO=Mg(C₂H₅CHO)⁽¹⁺⁾ 
• 7439-95-4 magnesium 

Downstream Products

• 71-41-0 pentan-1-ol 
• 626-93-7 n-hexan-2-ol 
• 71-23-8 propan-1-ol 
• 113353-87-0 Mg⁽¹⁺⁾(n-PrCHO) 
• 15921-15-0 Mg⁽¹⁺⁾(n-BuOH) 
• 1471-03-0 allyl propyl ether 
• 937-61-1 benzyl propyl ether 
• 113353-85-8 Mg⁽¹⁺⁾*C₂H₅CHO=Mg(C₂H₅CHO)⁽¹⁺⁾ 
• 113353-83-6 Mg⁽¹⁺⁾*CH₃CHO=Mg(CH₃CHO)⁽¹⁺⁾ 
• 113353-82-5 Mg⁽¹⁺⁾*C₂H₅OH=Mg(C₂H₅OH)⁽¹⁺⁾ 
• 105-30-6 2-methylpentan-1-ol 

Relevant articles and documents

1,2,5-chalcogenadiazole-annulated tripyrazinoporphyrazines: Synthesis, spectral characteristics, and influence of the heavy atom effect on their photophysical properties

A series of low-symmetry ZnII, MgII, and metal-free porphyrazine derivatives with one 1,2,5-chalcogenadiazole ring (with S, Se or Te) and three pyrazines bearing tert-butylsulfanyls were synthesized. The absorption maxima of ZnII complexes lay at 660, 674, and 707 nm for S, Se, and Te, respectively, indicating increasing contribution of the 1,2,5-chalcogenadiazole rings to the π-electronic system. Photophysical studies revealed that introduction of Se as a chalcogen and ZnII as a central metal causes an increase in the singlet oxygen quantum yield, reaching a value of 0.81, whereas the combination of S and MgII gives only 0.39. This takes place on the account of the fluorescence quantum yields that differ significantly from 0.072 (ZnII+Se) to 0.51 (MgII+S). These results demonstrated the two-dimensional heavy atom effect combining the role of the chalcogen (first dimension) as well as the central metal (second dimension). Attempts to prepare oxygen-containing isologues led to the formation of an unexpected side product.

Synthesis, photophysical and electrochemical properties of a D-σ-A ensemble derived from porphyrazine and tetrathiafulvalene

Cis/trans 1,2-dicyanoethylenes bearing tetrathiafulvalene units linked by a ethylenedithio spacer were prepared. The eis isomer was converted to eight tetrathiafulvalene unit substituted magnesium porphyrazine upon a metal-templated cyclotetramerization with magnesium propoxide in propanol. The dicyanoethylenes and target compound were characterized by EA, NMR, and MALDI-TOF mass and photophysical and Electrochemical properties were discussed.

Process for the preparation of pure alkaline earth alkoxides

Production of a metal-free Group II alkaline earth dimethanolate involves alcoholysis of the corresponding diethanolate with an excess of methanol.