35785-63-8

Upstream product

• 19879-84-6 tetraacetyl thioglucose 
• 100-11-8 1-bromomethyl-4-nitro-benzene 
• 604-69-3 β-D-glucose pentaacetate 
• 39549-05-8 bis(4-nitrobenzyl)disulfide 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 19879-84-6 O²,O³,O⁴,O⁶-Tetraacetyl-1-thio-D-glucose 

Downstream Products

• 161761-58-6 Acetic acid (2R,3R,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-{4-[6-(2,2,2-trifluoro-acetylamino)-hexanoylamino]-benzylsulfanyl}-tetrahydro-pyran-4-yl ester 
• 161761-60-0 6-[6-(2,2,2-Trifluoro-acetylamino)-hexanoylamino]-hexanoic acid [4-((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-ylsulfanylmethyl)-phenyl]-amide 
• 161761-61-1 1-deoxy-1-benzythio>-β-D-glucopyranose 
• 161761-59-7 1-deoxy-1--β-D-glucopyranose 
• 3947-62-4 2,3,4,5-tetra-O-acetyl-D-glucopyranose 
• 161761-57-5 2,3,4,6-tetra-O-acetyl-1-deoxy-1-(p-aminobenzylthio)-β-D-glucopyranose 

Relevant academic research and scientific papers

Modified one-pot protocol for the preparation of thioglycosides from unprotected aldoses via S-glycosyl isothiouronium salts

An efficient one-pot protocol for the direct preparation of thioglycosides starting from unprotected reducing sugars via S-glycosyl isothiouronium salts is reported. In this one-pot methodology, BF3·OEt2 has been used as a general catalyst for both per-O-acetylation of sugars and conversion of sugar per-O-acetates into S-glycosyl isothiouronium salts, which was allowed to react with alkylating agents in the presence of a base to furnish thioglycosides in excellent yield. Copyright Taylor & Francis, Inc.

Synthesis of thio- and selenoglycosides by cleavage of dichalconides in the presence of zinc/zinc chloride and reaction with glycosyl bromides

A convenient odorless methodology has been devised for the preparation of 1,2-trans-thio- and selenoglycosides through zinc-mediated cleavage of disulfides and diselenides and reaction of the thiolate and selenides formed in situ with glycosyl bromides. T

SYNTHESIS OF A LIGAND BASED ON 1-DEOXY-1-(p-AMINOBENZYLTHIO)-β-D-GLUCOPYRANOSE FOR AFFINITY CHROMATOGRAPHY

A synthesis is reported of 1-deoxy-1-benzylthio>-β-D-glucopyranose, which can be used as a ligand in purification of β-glucosidase by affinity chromatography.The ligand has been obtained by N-acylation of 1-deoxy-1-(p-aminobenzylthio)glucose with 6-(trifluoroacetamido)hexanoic acid, followed by complete deacylation.The corresponding amino derivative was obtained by reduction of 1-deoxy-1-(p-nitrobenzylthio)-β-D-glucopyranose with zinc dust.