3583-56-0Relevant academic research and scientific papers
Catalytic asymmetric [3,3]-rearrangements of allylic acetimidates
Moritz Bauer,Peters, René
, p. 2340 - 2346 (2015)
A streamlined synthetic access to enantiomerically pure allylic amines as advanced and valuable synthetic building blocks is important for pharmaceutical sciences. The rearrangement of allylic trihaloacetimidates is known as an attractive method to furnis
Synthesis of 3-aryl-5-methyl 4-substituted [1,2,4]triazoles
Lindstroem, Johan,Johansson, Martin
, p. 2217 - 2229 (2007/10/03)
Treatment of N -substituted acetamides with oxalyl chloride generates imidoyl chlorides, which react readily with aryl hydrazides. Following cyclization, triazoles can easily be obtained in moderate to good yields. 5-Methyl triazoles can be further functionalized through α-lithiation and subsequent reaction with an electrophile. Copyright Taylor & Francis Group, LLC.
