358336-41-1Relevant academic research and scientific papers
A new pd-catalyzed cascade reaction for the synthesis of strained aromatic polycycles
Blond, Gaelle,Bour, Christophe,Salem, Bahaa,Suffert, Jean
supporting information; body text, p. 1075 - 1078 (2009/04/06)
Two new palladium catalyzed cascade reactions involving a 4-exo-dig cyclocarbopalladation are described. These processes are shown to convert bromoenediynes and bromodienynes into strained aromatic compounds in a single step.
Silicon-initiated carbonylative carbotricyclization and [2+2+2+1] cycloaddition of enediynes catalyzed by rhodium complexes
Bennacer, Bibia,Fujiwara, Masaki,Lee, Seung-Yub,Ojima, Iwao
, p. 17756 - 17767 (2007/10/03)
The reaction of dodec-11-ene-1,6-diynes or their heteroatom congeners with a hydrosilane catalyzed by Rh(acac)(CO)2 at ambient temperature and pressure of CO gives the corresponding fused 5-7-5 tricyclic products, 5-oxo-1,3a,4,5,7,9-hexahydro-3
Facile synthesis of bicyclic and tricyclic skeletons by cycloisomerizations of hept-1-en-6-ynes and 4,9-diheteradodeca-1,11-dien-6-ynes, followed by [4 + 2] cycloadditions
Van Boxtel, Lonneke J.,Koerbe, Stefanie,Noltemeyer, Mathias,De Meijere, Armin
, p. 2283 - 2292 (2007/10/03)
Palladium-catalyzed intramolecular cross coupling of various 4-substituted hept-1-en-6-ynes, followed by intermolecular [4 + 2] cycloaddition with methyl acrylate and 2-chloro-2- cyclopropylideneacetate yielded both all-carbon and heteroanalogous bicyclic
