358359-37-2Relevant academic research and scientific papers
Convenient procedure for one-pot conversion of azides to N-monomethylamines
Kato,Ohmori,Suzuki
, p. 1003 - 1005 (2001)
One-pot conversion of azides to N-monomethylamines is described. Two optional protocols have been developed, which share the first stage, the reaction of an azide with (CH3)3P to generate the corresponding iminophosphorane. This Staudinger intermediate, thus generated, is either methylated with CH3I and hydrolyzed (method A), or treated with (HCHO)n and reduced with NaBH4 (method B), thereby giving the corresponding N-monomethylamine in high yield.
General synthesis route to benanomicin-pradimicin antibiotics
Tamiya, Minora,Ohmori, Ken,Kitamura, Mitsuru,Kato, Hirohisa,Arai, Tadamasa,Oorui, Mami,Suzuki, Keisuke
, p. 9791 - 9823 (2008/09/18)
A general approach to the regio- and stereoselective total synthesis of the benanomicin-pradimicin antibiotics (BpAs) is described. Construction of the aglycon has been achieved by 1)the diastereoselective ring-opening of a biaryl lactone by using (R)-val
