35854-86-5

Basic information

• Product Name: 6-Nonen-1-ol, (6Z)-
• Synonyms: (Z)-6-Nonen-1-ol
• CAS NO: 35854-86-5
• Molecular Formula: C₉H₁₈O
• Molecular Weight: 142.2386
• EINECS: 252-764-1
• Product Categories: Alphabetical Listings;Flavors and Fragrances;M-N
• Mol File: 35854-86-5.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 201.027 °C at 760 mmHg
• Flash Point: 74.248 °C
• Appearance: Colorless to pale yellow liquid
• Density: 0.85 g/cm³
• Vapor Pressure: 0.0777mmHg at 25°C
• Refractive Index: 1.451
• PKA: 15.18±0.10(Predicted)
• BRN: 2322878
• CAS DataBase Reference: 6-Nonen-1-ol, (6Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 6-Nonen-1-ol, (6Z)-(35854-86-5)
• EPA Substance Registry System: 6-Nonen-1-ol, (6Z)-(35854-86-5)

Safety Data

• Statements: 36/37/38
• Safety Statements: S23:Do not inhale gas/fumes/vapour/spray.; S24/25:Avoid contact with skin and eyes.
• WGK Germany: 3
• TSCA: Yes
• Hazardous Substances Data: 35854-86-5(Hazardous Substances Data)

Usage

Chemical Properties

Different sources of media describe the Chemical Properties of 35854-86-5 differently. You can refer to the following data:
1. White to slightly yellow liquid; powerful, melon-like odor.Insoluble in water.
2. cis-6-Nonen-1-ol has a powerful, melon, green odor.

Occurrence

Reported found in muskmelon, cucumber, lean fish and pepino fruit (Solanum muricatum)

Uses

Food additive.

Taste threshold values

Taste characteristics at 25 ppm: waxy, cucumber, honeydew, green watermelon.

Synthesis Reference(s)

The Journal of Organic Chemistry, 47, p. 4482, 1982 DOI: 10.1021/jo00144a016Synthesis, p. 920, 1984 DOI: 10.1055/s-1984-31017

InChI:InChI=1/C9H18O/c1-2-3-4-5-6-7-8-9-10/h3-4,10H,2,5-9H2,1H3/b4-3-

Upstream product

• 118794-69-7 6-[(tert-butyldimethylsilyl)oxy]hexanal 
• 103202-59-1 6-(tert-butyldimethylsilyl)oxyhexan-1-ol 
• 629-11-8 1,6-hexanediol 
• 1136196-28-5 C₁₅H₃₂OSi 
• 7348-78-9 (Z)-1-bromo-2-pentene 
• 146964-28-5 Methyl 6-diphenylphosphinoylhexanoate 
• 89625-22-9 1-(6-tert-Butyldimethylsilyloxyhexyl)diphenylphosphine Oxide 
• 73367-77-8 (5-carboxypentyl)diphenylphosphine oxide 
• 19100-95-9 diphenyl(6-hydroxy-n-hex-1-yl)phosphine oxide 
• 43125-21-9 (Z)-hex-3-en-1-ylmagnesium bromide 
• 60171-36-0 (Z)-Oct-2-ene-1,8-diol 
• 119265-30-4 1,8-diacetoxy-2Z-octene 
• 74-88-4 methyl iodide 
• 146964-30-9 (6R,7S)-6-(Diphenyl-phosphinoyl)-nonane-1,7-diol 

Downstream Products

• 2277-19-2 cis-6-nonenal 
• 76238-22-7 cis-non-6-en-1-yl acetate 
• 3937-56-2 1,9-Nonanediol 
• 4469-84-5 1,7-nonanediol 
• 61448-29-1 1,8-dihydroxynonane 
• 143-08-8 nonyl alcohol 
• 36508-31-3 (Z)-oxacycloheptadec-11-en-2-one 
• 36508-31-3 (E)-oxacycloheptadec-11-en-2-one 
• 42036-73-7 1-((E)-non-1-enyl)benzene 
• 111735-48-9 (Z)-1-(non-1-enyl)benzene 
• 1431631-38-7 C₁₇H₂₄O₃ 
• 1431631-76-3 C₁₇H₂₆O₃ 
• 1352945-56-2 (Z)-non-6-enylphenylamine 
• 1003294-17-4 4-nitrophenyl-(Z)-6-nonen-1-yl carbonate 

Relevant articles and documents

A general strategy for the stereocontrolled preparation of diverse 8- and 9-membered Laurencia -type bromoethers

A unique procedure to effect a ring-expanding bromoetherification process is described, wherein tetrahydrofurans and tetrahydropyrans are smoothly transformed into 8- and 9-membered bromoethers in a regio- and stereocontrolled manner through the use of BDSB (bromodiethylsulfonium bromopentachloroantimonate). These products resemble the cores of the Laurencia C15 acetogenins. In light of the generality and effectiveness of the approach, this work provides a unique strategy for their laboratory preparation and may implicate a possible biosynthesis pathway.

Syntheses of the sex pheromone components of wild silk moths, fruit fly, melon fly and olive fly

-

SYNTHESIS OF SINGLE ISOMERS (E OR Z) OF UNSATURATED ALCOHOLS BY THE HORNER-WITTIG REACTION

Single isomers (E or Z) of homoallylic and higher alcohols can be synthesised from ω-hydroxyalkyldiphenylphosphine oxides and aldehydes, or from alkyldiphenylphosphine oxides and lactones