103202-59-1

Basic information

• Product Name: 1-Hexanol, 6-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-
• CAS NO: 103202-59-1
• Molecular Formula: C12H28O2Si
• Molecular Weight: 232.439
• Mol File: 103202-59-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-Hexanol, 6-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Hexanol, 6-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-(103202-59-1)
• EPA Substance Registry System: 1-Hexanol, 6-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-(103202-59-1)

Safety Data

• Hazardous Substances Data: 103202-59-1(Hazardous Substances Data)

Upstream product

• 653564-21-7 6-(tert-butyldimethylsilyloxy)hexyl acetate 
• 874796-87-9 1-(tert-butyldimethylsilyloxy)-6-(triethylsilyloxy)-hexane 
• 846539-31-9 tert-butyldimethyl{[6-({4-[(trimethylsilyl)methyl]benzyl}oxy)hexyl]oxy}silane 
• 67-56-1 methanol 

Downstream Products

• 846539-31-9 tert-butyldimethyl{[6-({4-[(trimethylsilyl)methyl]benzyl}oxy)hexyl]oxy}silane 
• 926030-05-9 tert-butyl-[6-(4-butyl-phenoxy)-hexyloxy]-dimethyl-silane 
• 6376-95-0 trans-2-vinylcyclohexanol 
• 6376-95-0 (1RS,2RS)-2-vinylcyclohexanol 
• 130157-26-5 2-[6-(2-Benzyloxycarbonylamino-acetylsulfanyl)-hexyloxy]-6-[6-((S)-2-tert-butoxycarbonylamino-propionylsulfanyl)-hexyloxy]-benzoic acid tert-butyl ester 
• 130157-30-1 2-[6-(2-Benzyloxycarbonylamino-acetylsulfanyl)-hexyloxy]-6-[6-((S)-2-tert-butoxycarbonylamino-propionylsulfanyl)-hexyloxy]-benzoic acid methyl ester 
• 131326-45-9 2-[6-(2-Benzyloxycarbonylamino-acetylsulfanyl)-hexyloxy]-6-(6-mercapto-hexyloxy)-benzoic acid tert-butyl ester 
• 131326-47-1 2-[6-(2-Benzyloxycarbonylamino-acetylsulfanyl)-hexyloxy]-6-(6-mercapto-hexyloxy)-benzoic acid methyl ester 
• 131355-34-5 2,6-Bis-[6-(tert-butyl-dimethyl-silanyloxy)-hexyloxy]-benzoic acid tert-butyl ester 
• 131326-34-6 2,6-Bis-[6-(tert-butyl-dimethyl-silanyloxy)-hexyloxy]-benzoic acid methyl ester 
• 131326-37-9 2,6-Bis-(6-acetylsulfanyl-hexyloxy)-benzoic acid tert-butyl ester 
• 131326-38-0 2,6-Bis-(6-acetylsulfanyl-hexyloxy)-benzoic acid methyl ester 
• 130157-18-5 2,6-Bis-(6-mercapto-hexyloxy)-benzoic acid tert-butyl ester 
• 131326-35-7 2,6-Bis-(6-hydroxy-hexyloxy)-benzoic acid tert-butyl ester 

Relevant articles and documents

N,N-diarylammonium pyrosulfate as a highly effective reverse micelle-type catalyst for hydrolysis of esters

Reverse micelle-type N,N-diarylammonium pyrosulfate (3-5 mol %) efficiently catalyzes the hydrolysis of esters (up to 100 mmol scale) under organic solvent-free conditions. The present method is successfully applied to the hydrolysis of various esters without the decomposition of the base-sensitive moieties and without any loss of optical purity for α-heterosubstituted carboxylic acids.

The trimethylsilyl xylyl (TIX) ether: A useful protecting group for alcohols

A new protecting group for alcohols, the p-trimethylsilyl xylyl (TIX) group has been developed. The TIX group is used to protect various alcohols under acidic as well as basic conditions. The protected ethers thus formed had noteworthy chemoselectivity upon deprotection in the presence of other benzyl ethers and commonly used protecting groups. The stability of the TIX group towards various reagents has also been examined.

On the Selective Deprotection of Trityl Ethers

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