35865-00-0Relevant academic research and scientific papers
Adducts of Triallylborane with Ammonia and Aliphatic Amines as Stoichiometric Allylating Agents for Aminoallylation Reaction of Carbonyl Compounds
Kuznetsov, Nikolai Yu.,Tikhov, Rabdan M.,Strelkova, Tatiana V.,Bubnov, Yuri N.
, p. 3549 - 3552 (2018)
Triallylborane-amines adducts are effective stoichiometric allylating agents in the aminoallylation reaction of carbonyl compounds in methanol. Moreover, copper-catalyzed diastereoselective allylation of Ellman's imine was achieved with triallylborane-methylamine adduct.
Formation of N,N'-Disubstituted Methanediamine Derivatives from Hexamethyldisilazane and Aldehydes via Stepwise Reactions
Nishiyama, Kozaburo,Saito, Masaki,Oba, Makoto
, p. 609 - 611 (2007/10/02)
The ZnCl2-catalyzed reaction of aldehydes with hexamethyldisilazane (HMDS) resulted in the formation of N,N'-disubstituted methanediamines, which were found to be formed stepwisely via 1:1- and 1:2-adducts of HMDS and aldehydes.
