35877-44-2Relevant academic research and scientific papers
ACID-CATALYZED DECOMPOSITION OF DIAZO CARBONYL COMPOUNDS. II. SYNTHESIS OF 2- OR 5-HETEROATOM-SUBSTITUTED OXAZOLES.
Ibata,Yamashita,Kashiuchi,Nakano,Nakawa
, p. 2450 - 2455 (2007/10/02)
The BF//3-catalyzed decomposition of m- and p-substituted alpha -diazoacetophenones in excess of methyl thiocyanate and ethyl thiocyanate gave the corresponding 2-methylthio-, and 2-ethylthio-5-aryloxazoles, respectively in good yields along with s-alkyl-
THE BF3-CATALYZED DECOMPOSITION OF DIAZO CARBONYL COMPOUNDS IN NITRILES. FORMATION OF ENAMIDES
Ibata, Toshikazu,Yamamoto, Masahiko
, p. 161 - 164 (2007/10/02)
The BF3-catalyzed decomposition of α-diazoacetophenones in acetonitrile, propionitrile, or methyl thiocyanate in the presence of 1,3,5-trimethoxybenzene produced enamides (7) in good yield.
