35879-90-4Relevant academic research and scientific papers
Acid-catalysed Rearrangement of Terpinolene Oxide
Gurudutt, K. N.,Pasha, M. A.,Ravindranath, B.
, p. 820 - 823 (2007/10/02)
The title reaction has been examined in detail and the effects of solvent and the acid catalyst on the nature of the products elucidated.Novel 1,3-dioxolanes, with potential use as aroma chemicals, have been prepared from terpinolene oxide (2) by an efficient method.
LEWIS ACID CATALYSED PINACOL REARRANGEMENT - A SHORT SYNTHESIS OF KARAHANAENONE
Bhushan, Vidya,Chandrasekaran, Srinivasan
, p. 1537 - 1538 (2007/10/02)
The pinacolic coupling reaction has been effectively used to prepare the unsymmetrical pinacol 2 and this key intermediate underwent a smooth ring enlargement to the monoterpene karahanaenone 3, an odoriferous constituent of Japanese hop and Cypress oil.
