35896-43-6Relevant academic research and scientific papers
N-NITRENES. II. INVESTIGATION OF THE MECHANISM OF DISSOCIATION OF DIBENZYLAMINONITRENE BY CHEMICALLY INDUCED POLARIZATION OF 1H NUCLEI. THE SPIN STATE OF DIBENZYLAMINONITRENE
Savin, V. I.
, p. 15 - 25 (2007/10/02)
The mechanism of the dissociation of dibenzylaminonitrene and p-bromodibenzylaminonitrene into molecular nitrogen and hydrocarbon products was studied.Dibenzylaminonitrene forms dibenzyl and o- and p-benzyltoluenes.In the presence of thiophenol significant amounts of toluene are formed.During dissociation p-bromodibenzylaminonitrene gives a mixture of symmetrical and unsymmetrical dibenzyls.In the presence of octanethiol only unsymmetrical p-bromodibenzyl is formed.The dissociation of dibenzylaminonitrene takes place by synchronous cleavage of the two C-N bonds and the formation of a pair of benzyl radicals.Dibenzylaminonitrene dissociates from the singlet electronic state.
REACTIONS OF AROMATIC NITRO COMPOUNDS. LVI. REACTION OF POLYNITRODIPHENYL SULFONES WITH ACETONE AND POTASSIUM HYDROXIDE
Alekhina, N. N.,Gitis, S. S.,Grudtsyn, Yu. D.,Kaminskii, A. Ya.
, p. 1138 - 1142 (2007/10/02)
The Yanovskii ? complexes of 2,4-dinitrophenyl sulfone and 2,4-dinitro-, 2,4,4'-trinitro-, and 2,2',4,4'-tetranitrodiphenylsulfones were obtained and isolated in the crystalline form.It was established by PMR, IR, and electronic spectroscopy that they are
