55932-12-2

Upstream product

• 64-17-5 ethanol 
• 1137-73-1 N,N-bis(carboxymethyl)aniline 
• 21911-77-3 ethyl 2-(N-ethyl-N-phenylamino)acetate 
• 105-36-2 ethyl bromoacetate 
• 62-53-3 aniline 
• 623-73-4 diazoacetic acid ethyl ester 
• 2623-87-2 bromobutyric acid 
• 91-66-7 N,N-diethylaniline 

Downstream Products

• 618113-12-5 [(4-(anthracen-9-ylmethyl)-phenyl)-ethoxycarbonyl-methyl-amino]-acetic acid ethyl ester 
• 618113-14-7 [(4-{10-[4-(bis-ethoxycarbonylmethyl-amino)benzyl]-anthracen-9-ylmethyl}-phenyl)-ethoxycarbonyl-methyl-amino]-acetic acid ethyl ester 
• 27919-79-5 ehyl 2-[N-ethoxyformyl methyl-N-(4-formylphenyl)]amino acetate 
• 112335-76-9 [(4-aminophenyl)ethoxycarbonylmethylamino]acetic acid ethyl ester 
• 1421059-65-5 C₃₁H₂₉N₃O₄ 
• 1421059-66-6 C₂₇H₂₁N₃O₄ 
• 1421059-64-4 C₃₁H₃₁N₃O₄ 
• 1402091-14-8 C₁₄H₂₃N₅O₂ 
• 1402091-15-9 C₂₄H₃₀N₆O₄ 
• 1357262-52-2 (E)-diethyl 2,2'-((4-(2-(4-(dicyanomethylene)-4H-chromen-2-yl)vinyl)phenyl)azanediyl)diacetate 

Relevant academic research and scientific papers

Cd(II) Sensing in Water Using Novel Aromatic Iminodiacetate Based Fluorescent Chemosensors

(Equation presented) Compounds 1 and 2 were designed as fluorescent chemosensors for Cd(II). For both, a selective determination of Cd(II) over Zn(II) was achieved. The fluorescence emission of both was pH-independent and switched off between pH 3-11 in 1

Selective carbene transfer to amines and olefins catalyzed by ruthenium phthalocyanine complexes with donor substituents

Electron-rich ruthenium phthalocyanine complexes were evaluated in carbene transfer reactions from ethyl diazoacetate (EDA) to aromatic and aliphatic olefins as well as to a wide range of aromatic, heterocyclic and aliphatic amines for the first time. It was revealed that the ruthenium octabutoxyphthalocyanine carbonyl complex [(BuO)8Pc]Ru(CO) is the most efficient catalyst converting electron-rich and electron-poor aromatic olefins to cyclopropane derivatives with high yields (typically 80-100%) and high TON (up to 1000) under low catalyst loading and nearly equimolar substrate/EDA ratio. This catalyst shows a rare efficiency in the carbene insertion into amine N-H bonds. Using a 0.05 mol% catalyst loading, a high amine concentration (1 M) and 1.1 eq. of EDA, a number of structurally divergent amines were selectively converted to mono-substituted glycine derivatives with up to quantitative yields and turnover numbers reaching 2000. High selectivity, large substrate scope, low catalyst loading and practical reaction conditions place [(BuO)8Pc]Ru(CO) among the most efficient catalysts for the carbene insertion into amines.

Polydentate ligand terpyridyl diacetate and preparation method thereof

The invention discloses polydentate ligand terpyridyl diacetate. The molecular formula is C25H20N4O4, and the molecular weight is 440. The name of the compound is 4;-p-N,N-dihydroxyethyl aminophenyl-2,2':6,2''-terpyridyl. The coordination capacity of terp

Fluorescent probe for detecting metal ion content in water, and applications thereof

The invention discloses a fluorescent probe for detecting the metal ion content in water, wherein a rhodamine fluorophore is introduced into the molecule of N-aniline acetate used as a metal ion complex to generate the fluorescent indicator for metal ions

Fluorescent probe for detecting content of metal ions in water and application of fluorescent probe

The invention discloses a fluorescent probe for detecting the content of metal ions in water. N-carbethoxy aniline is used as a metal ion complex of the compound, and fluorescein fluorophore is introduced into the molecule of the metal ion complex to gene

Dual role of Cu2O nanocubes as templates and networking catalysts for hollow and microporous Fe-porphyrin networks

Cu2O nanocubes were used for the synthesis of hollow and microporous Fe porphyrin networks (H-MFePN). In this synthesis, Cu2O nanocubes performed not only as networking catalysts but also as shape controlling templates. MFePN were formed on the surface of the Cu2O nanocubes through azide-alkyne cycloaddition of tetrakis(4-ethynylphenyl) Fe-porphyrin with 1,4-diazidobenzene. H-MFePN showed excellent catalytic activities in carbene insertion into N-H bonds, maintaining their activities during five recycle tests.

Unexpected formation of a μ-carbido diruthenium(IV) complex during the metalation of phthalocyanine with Ru3(CO)12 and its catalytic actIVity in carbene transfer reactions

A μ-carbido diruthenium(iv) phthalocyanine complex was prepared for the first time from the free-base octabutoxyphthalocyanine by direct metalation with Ru3(CO)12. The first examples of the catalytic activity of Ru(iv) binuclear phthalocyanines were demonstrated by the cyclopropanation of aromatic olefins and carbene insertion into the N-H bonds of aromatic or aliphatic amines with turnover numbers of 680-1000 and 580-1000, respectively.

Halides tuning the subcellular-targeting in two-photon emissive complexes: Via different uptake mechanisms

We reported a simple and universal strategy by tuning halides (Cl, Br and I) in terpyridine-Zn(ii) complexes to achieve different subcellular organelle targeting (nucleolus, nucleus and intracellular membrane systems, respectively) via different cellular

A water-soluble two-photon fluorescence chemosensor for ratiometric imaging of mitochondrial viscosity in living cells

A convenient and rationally designed water-soluble two-photon excited fluorescence (TPEF) sensor for monitoring viscosity with specific targeting at the subcellular level remains a challenge. Herein, we reported a novel water-soluble ratiometric TPEF chem

Hemin-Catalyzed, Cyclodextrin-Assisted Insertion of Carbenoids into N-H Bonds

An aqueous hemin-catalyzed, cyclodextrin-assisted N-H insertion reaction of α-diazo ester into aromatic amines is described here. This aqueous catalytic system showed good compatibility with various arylamines, with yields up to 96%. A size-controlled reaction phenomenon by different cyclodextrins (CDs) was also observed when ethyl diazoacetate (EDA) was used. The reaction mechanism was also preliminarily proposed on the basis of designed control experiments.