35905-41-0Relevant articles and documents
The Reaction of Some α-Oxygenated Cyclic Ketones with Sulfur Ylides
Marschner, Christoph,Baumgartner, Judith,Griengl, Herfried
, p. 999 - 1004 (2007/10/02)
Cyclopentanones 1, 4 and 7, as well as uloses 11, 14, 17 and 20, all possessing an oxygen atom in α-position with respect to the carbonyl group, have been allowed to react with dimethylsulfonium and dimethyloxosulfonium methylides.It has been found that t
Synthetic Routes to 6,8-Dioxabicyclooctyl Pheromones from D-Glucose Derivatives. 3. Synthesis of (-)-Frontalin
Jarosz, Slawomir,Hicks, David R.,Fraser-Reid, Bert
, p. 935 - 940 (2007/10/02)
3-Deoxy-2-oxo glycosides with and without a C4 hydroxyl group are readily prepared from methyl α-D-glucopyranoside.Reaction with methylmagnesium iodide gives the C2 tertiary alcohol with an axially oriented methyl group.The epimeric tertiary alcohol can b