35942-95-1Relevant academic research and scientific papers
"Furan endwise peeling" of celluloses: Mechanistic studies and application perspectives of a novel reaction
Yoneda, Yuko,Krainz, Karin,Liebner, Falk,Potthast, Antje,Rosenau, Thomas,Karakawa, Makoto,Nakatsubo, Fumiaki
, p. 475 - 484 (2008/09/18)
The mechanism of a novel reaction type, the "furan endwise peeling" reaction, has been studied. Making extensive use of experiments on model compounds, the structural prerequisites to the reaction were found to be a 2-hydroxpyran β-glycosidically linked t
The scope of catalytic asymmetric hydroboration/oxidation with rhodium complexes of 1,1'-(2-diarylphosphino-1-naphthyl)isoquinolines
Doucet, Henri,Fernandez, Elena,Layzell, Timothy P.,Brown, John M.
, p. 1320 - 1330 (2007/10/03)
Preformed cationic Rh complexes of the title ligands are effective for the asymmetric hydroboration/oxidation of vinylarenes at ambient temperature. These vinylarenes may carry E- or Z-β substituents but not a substituents. Enantiomer excesses of up to 97% can be obtained in the most favourable cases. The enantioselectivity is moderately sensitive to the structure of the ligand: the difurylphosphino ligand gave superior results for electron-poor styrenes and the diphenylphosphino ligand the best results for electron-rich reactants. Mechanistic aspects are discussed.
ANOMALUS BEHAVIOUR IN SOME NUCLEOPHILIC RING OPENING OF FURYL-2-OXIRANE
Alcaide, Benito,Areces, Pilar,Borredon, Elisabeth,Biurrun, Cristina,Castellas, Javier P.,Plumet, Joaquin
, p. 1997 - 2002 (2007/10/02)
The behaviour of furyl-2-oxirane in some nucleophilic ring opening reactions was studied.
