35964-48-8

Basic information

• Product Name: bis(4-chloro-3-nitrophenyl) disulphide
• Synonyms: bis(4-chloro-3-nitrophenyl) disulphide;Bis(4-chloro-3-nitrophenyl) persulfide
• CAS NO: 35964-48-8
• Molecular Formula: C₁₂H₆Cl₂N₂O₄S₂
• Molecular Weight: 377.22304
• EINECS: 252-818-4
• Mol File: 35964-48-8.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 497.1 °C at 760 mmHg
• Flash Point: 254.4 °C
• Appearance: /
• Density: 1.68 g/cm³
• Vapor Pressure: 1.56E-09mmHg at 25°C
• Refractive Index: 1.729
• CAS DataBase Reference: bis(4-chloro-3-nitrophenyl) disulphide(CAS DataBase Reference)
• NIST Chemistry Reference: bis(4-chloro-3-nitrophenyl) disulphide(35964-48-8)
• EPA Substance Registry System: bis(4-chloro-3-nitrophenyl) disulphide(35964-48-8)

Safety Data

• Hazardous Substances Data: 35964-48-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H6Cl2N2O4S2/c13-9-3-1-7(5-11(9)15(17)18)21-22-8-2-4-10(14)12(6-8)16(19)20/h1-6H

Upstream product

• 97-08-5 3-nitro-4-chlorosulfonyl chloride 
• 17691-19-9 4-chloro-3-nitrobenzenesulphonic acid sodium salt 

Downstream Products

• 1199-36-6 1-chloro-4-(methylthio)-2-nitrobenzene 
• 1349338-07-3 3,3'-disulphanediylbis(6-chloroaniline) 
• 404-73-9 1-chloro-2-nitro-4-(trifluoromethylthio)benzene 
• 2613-26-5 3-nitrophenylsulfur pentafluoride 
• 349-04-2 4-chloro-3-nitrobenzenesulfonyl fluoride 
• 165114-87-4 1-chloro-2-nitro-4-(pentafluorosulfanyl)benzene 

Relevant articles and documents

ARYL SULFIDE DERIVATIVES AND ARYL SULFOXIDE DERIVATIVES AS ACARICIDES AND INSECTICIDES

The present invention relates to aryl sulphide and aryl sulphoxide derivatives, to their use as acaricides and insecticides for controlling animal pests and to processes and intermediates for their preparation. The aryl sulphide and aryl sulphoxide derivatives have the general structure (I) in which the respective radicals have the meanings given in the description.

New 4-pentafluorosulfanyl and 4-perfluoroalkylthio derivatives of 1-chloro-2-nitro- and 1-chloro-2,6-dinitrobenzenes

New 4-pentafluorosulfanyl and 4-perfluoroalkylthio derivatives of 1-chloro-2-nitrobenzene and 1-chloro-2,6-dinitrobenzene were prepared from the corresponding bis(4-chloro-3-nitrophenyl)disulfide and bis(4-chloro-3,5-dinitrophenyl)disulfide, respectively. The SF5 derivatives were obtained by fluorination of the disulfides with AgF2 according to Sheppard's method, while perfluoroalkylation was carried out by means of thermolytic reactions with xenon(II) bis(perfluoroalkylcarboxylates). The introduction of fluorine-containing, electron-withdrawing substituents into the aromatic ring (in the presence of other deactivating groups) reinforces the activation of the halogen substituent towards nucleophilic attack. Several nucleophilic substitution reactions have been carried out with these compounds, and as a result, some N- and S-containing groups were introduced in the benzene ring. For example, the previously unknown SF5, CF3S, and C2F5S analogues of trifluralin (Treflan) were prepared and characterized. Additional synthetic possibilities for heterocyclic chemistry are presented on the basis of reactions of the new 1-chloro-2,6-dinitrobenzene derivatives with ethyl thioglycolate wherein fluorine-containing derivatives of benzothiazole N-oxide were obtained as the main products.