359678-99-2Relevant academic research and scientific papers
Quinine-catalyzed enantioselective desymmetrization of meso-aziridines with benzenethiols
Wang, Zhiyong,Sun, Xiaoyu,Ye, Shengqing,Wang, Weizi,Wang, Bing,Wu, Jie
, p. 964 - 969 (2008)
Ring opening of meso-aziridines with benzenethiols utilizing quinine as an organocatalyst has been developed. The reaction proceeded smoothly in the presence of 10 mol % of quinine in CHCl3 to afford β-amino sulfides in high yields and with mod
Tributylphosphine: A remarkable promoting reagent for the ring-opening reaction of aziridines
Hou, Xue-Long,Fan, Ren-Hua,Dai, Li-Xin
, p. 5295 - 5300 (2002)
Tributylphosphine was found to be an effective promoting reagent for ring opening of a variety of aziridines and nucleophiles to produce anti-bifunctional products in good to excellent yield. The study showed that the reaction is initiated through the attack of tributylphosphine as a nucleophile at the carbon atom of the aziridine ring.
Bismuth triflate as novel and efficient catalyst for the synthesis of β-aminosulfides
Yadav, Jhillu S.,Reddy, B. V. Subba,Baishya, Gakul,Reddy, P. Venkatram,Harshavardhan
, p. 1854 - 1858 (2004)
Aziridines undergo ring opening readily with various thiols in the presence of 5 mol% bismuth triflate under very mild reaction conditions to afford the corresponding β-aminosulfides in excellent yields with high regioselectivity.
Polyethylene glycol (PEG) as an efficient recyclable medium for the synthesis of β-amino sulfides
Kamal, Ahmed,Reddy, D. Rajasekhar,Rajendar
, p. 2261 - 2264 (2006)
Aziridines undergo ring opening readily with various thiols in the presence of polyethylene glycol (PEG) to afford the corresponding β-amino sulfides in high yields with good regioselectivity under mild and neutral conditions. The PEG can be recovered and
An efficient procedure for cleavage of aziridines with various thiols promoted by ZnCl2
Wu,Hou,Dai
, p. 1314 - 1317 (2007/10/03)
The ring-opening reaction of aziridines with various thiophenols and thiols catalyzed by ZnCl2 provides β-amino sulfides in high yield.
