359772-31-9

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 289505-45-9 1,6-Anhydro-3-azido-2-O-benzyl-3-deoxy-β-D-mannopyranose 
• 100-39-0 benzyl bromide 
• 3868-04-0 1,6:3,4-dianhydro-β-D-altropyranose 
• 213594-43-5 1,6:3,4-dianhydro-2-O-benzyl-β-D-altropyranose 

Downstream Products

• 1353759-02-0 1,6-anhydro-3-azido-3-deoxy-4-O-tosyl-β-D-mannopyranose 
• 1353759-03-1 C₁₃H₁₄FN₃O₅S 
• 848579-23-7 1,6-anhydro-2-O-benzyl-3,4-dideoxy-3,4-(N-o-nitrobenzenesulfonylepimino)-β-D-talopyranose 

Relevant academic research and scientific papers

Skeletal rearrangements resulting from reactions of 1,6:2,3- and 1,6:3,4-dianhydro-β-d-hexopyranoses with diethylaminosulphur trifluoride

A complete series of eight 1,6:2,3- and 1,6:3,4-dianhydro-β-d- hexopyranoses were subjected to fluorination with DAST. The 1,6:3,4- dianhydropyranoses yielded solely products of skeletal rearrangement resulting from migration of the tetrahydropyran oxygen

Synthesis and NMR spectra of 1,6-anhydro-2,3-dideoxy-2,3-epimino- and 1,6-anhydro-3,4-dideoxy-3,4-epimino-β-D-hexopyranoses

A complete series of 2,3-dideoxy-2,3-epimino-and 3,4-dideoxy-3,4-epimino-1,6-anhydro-β-D-hexopyranoses were prepared by lithium aluminum hydride reduction of the corresponding trans-azido tosylates or trans-azido epoxides of 1,6-anhydro-β-D-hexopyranoses. The structure of the epimino derivatives was confirmed by 1H and 13C NMR spectra.