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1-Iodo-4-((trifluoromethyl)sulfonyl)benzene is an organic compound with the chemical formula C7H4F3IOSO2. It is a derivative of benzene, featuring an iodine atom at the 1st position, a trifluoromethylsulfonyl group at the 4th position, and a total of 7 carbon atoms. 1-iodo-4-((trifluoromethyl)sulfonyl)benzene is known for its reactivity and is often used as an intermediate in the synthesis of various pharmaceuticals and agrochemicals. Its unique structure, with the combination of an iodine atom and a trifluoromethylsulfonyl group, provides it with specific properties that make it valuable in chemical reactions, such as electrophilic aromatic substitution. The compound is typically synthesized through the reaction of 1-iodo-4-nitrobenzene with trifluoromethanesulfonic anhydride. Due to its reactivity, it is important to handle 1-iodo-4-((trifluoromethyl)sulfonyl)benzene with care, following proper safety protocols.

360-01-0

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360-01-0 Usage

Chemical structure

A benzene ring with an iodine atom and a trifluoromethylsulfonyl group attached.

Common use

As a reagent in organic synthesis, particularly in the introduction of the trifluoromethylsulfonyl group into organic molecules.

Electron-withdrawing properties

Known for its strong electron-withdrawing properties, making it valuable in the modification and functionalization of organic molecules.

Industrial applications

Used in the pharmaceutical industry for the synthesis of new drug candidates and in the development of agrochemicals.

Handling and storage

It is important to handle and store 1-iodo-4-((trifluoromethyl)sulfonyl)benzene carefully due to its reactivity and potential toxicity.

Check Digit Verification of cas no

The CAS Registry Mumber 360-01-0 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 3,6 and 0 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 360-01:
(5*3)+(4*6)+(3*0)+(2*0)+(1*1)=40
40 % 10 = 0
So 360-01-0 is a valid CAS Registry Number.

360-01-0Relevant academic research and scientific papers

Electrophilic Triflyl-arylation and Triflyl-pyridylation by Unsymmetrical Aryl/Pyridyl-λ3-iodonium Salts: Synthesis of Aryl and Pyridyl Triflones

Das, Prajwalita,Shibata, Norio

supporting information, p. 11915 - 11924 (2017/11/24)

Unsymmetrical diaryl-λ3-iodonium salts containing aryl triflone (Ar-SO2CF3) were designed and synthesized. X-ray crystal structure analysis of the salt indicated a T-shaped geometry at the iodine atom. The salts were found to be powerful electrophilic reagents for triflyl-arylation of C-, N-, and O-centered nucleophiles under mild conditions. Electrophilic transfer of pyridine triflone (Py-SO2CF3) to nucleophiles was also realized by the use of corresponding triflylpyridyl-aryl-λ3-iodonium salts. Selection of auxiliaries (dummy ligands) of unsymmetrical diaryl-λ3-iodonium salts is crucial for this transformation.

METHOD FOR PRODUCING TRIFLUOROMETHYLSULFONYL COMPOUND DERIVATIVE

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Paragraph 0019-0020;0021-0023, (2017/05/12)

PROBLEM TO BE SOLVED: To provide a method for producing a trifluoromethylsulfonyl compound derivative useful as synthetic intermediates for medicines and agrochemicals. SOLUTION: The method for producing a trifluoromethylsulfonyl compound derivative repre

Organocatalyzed Trifluoromethylation of Ketones and Sulfonyl Fluorides by Fluoroform under a Superbase System

Okusu, Satoshi,Hirano, Kazuki,Tokunaga, Etsuko,Shibata, Norio

, p. 581 - 585 (2015/10/20)

Fluoroform (HCF3, HFC-23) is a side product in the manufacture of polytetrafluoroethylene (Teflon). Despite its attractive properties, taming HCF3 for trifluoromethylation is quite problematic owing to its low acidity and the labilit

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