360055-41-0Relevant academic research and scientific papers
Studies towards the biomimetic synthesis of bisesquiterpene lactones
Bagal, Sharanjeet K.,Adlington, Robert M.,Marquez, Rodolfo,Cowley, Andrew R.,Baldwin, Jack E.
, p. 4993 - 4996 (2003)
A possible biomimetic connection between atractylolide, hydroxyatractylolide and biatractylolide and biepiasterolide has been demonstrated by efficiently generating the biatractylolide and biepiasterolide core structures from atractylolide and hydroxyatra
Dimerization of butenolide structures. A biomimetic approach to the dimeric sesquiterpene lactones (±)-biatractylolide and (±)- biepiasterolide
Bagal, Sharanjeet K.,Adlington, Robert M.,Baldwin, Jack E.,Marquez, Rodolfo
, p. 9100 - 9108 (2007/10/03)
The biomimetic synthesis of the bisesquiterpene lactones (±)-biatractylolide 1 and (±)-biepiasterolide 2 via dimerization of the captodative stabilized radical 8 is reported. Atractylon 7 has also been shown to be a possible intermediate during the biosynthesis of biatractylolide 1, biepiasterolide 2, atractylolide 3, and hydroxyatractylolide 4.
Synthetic utility of stannyl enolates as radical alkylating agents
Miura, Katsukiyo,Fujisawa, Naoki,Saito, Hiroshi,Wang, Di,Hosomi, Akira
, p. 2591 - 2594 (2007/10/03)
(Equation presented) The radical-initiated β-ketoalkylation of haloalkanes with tributylstannyl enolates is described. Stannyl enolates derived from aromatic ketones are reactive toward the homolytic β-ketoalkylation of simple haloalkanes as well as those activated by an electron-withdrawing group. The reactivity of stannyl enolates as radical alkylating agents can be utilized for an efficient three-component coupling reaction among stannyl enolates, haloalkanes, and electron-deficient alkenes.
