36018-19-6

Basic information

• Product Name: Carbonochloridic acid, 2,3-dimethylphenyl ester
• Synonyms: 2,3-Dimethylphenyl-chlorameisensaeureester;2,3-Dimethylphenylchloroformate
• CAS NO: 36018-19-6
• Molecular Formula: C9H9ClO2
• Molecular Weight: 184.622
• Mol File: 36018-19-6.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 94 °C(Press: 12 Torr)
• Density: 1.195±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Carbonochloridic acid, 2,3-dimethylphenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbonochloridic acid, 2,3-dimethylphenyl ester(36018-19-6)
• EPA Substance Registry System: Carbonochloridic acid, 2,3-dimethylphenyl ester(36018-19-6)

Safety Data

• Hazardous Substances Data: 36018-19-6(Hazardous Substances Data)

Upstream product

• 32315-10-9 bis(trichloromethyl) carbonate 
• 526-75-0 2,3-Dimethylphenol 

Downstream Products

• 22132-57-6 α,α'-Dichloro-2,3-xylylchloroformiat 
• 443-82-3 3-fluoro-o-xylene 
• 608-23-1 3-chloro-o-xylene 
• 67404-16-4 2-(2,3-dimethyl-phenoxymethyl)-4,5-dihydro-imidazole-1-carboxylic acid 2,3-dimethyl-phenyl ester 
• 22134-28-7 α,α'-Dichlor-2,3-xylenyl-N-cyclohexylcarbamat 
• 22134-54-9 α,α'-Dichlor-2,3-xylenyl N-methylcarbamat 
• 22134-27-6 α,α'-Dichloro-2,3-xylyl-carbamat 

Relevant articles and documents

Visible-Light-Induced Intramolecular C(sp2)-H Amination and Aziridination of Azidoformates via a Triplet Nitrene Pathway

Catalytic intramolecular C-H amination and aziridination reactions of o-allylphenyl azidoformates have been achieved under visible-light irradiation, providing a mild, clean, and efficient method for the synthesis of useful benzoxazolones and [5.1.0] bicyclic aziridines. Mechanistic studies suggest that a triplet nitrene acts as the reactive intermediate. The chemoselectivity of the reaction, with alkyl olefin aziridination ? electron deficient olefin aziridination ≈ C(sp2)-H amination ? C(sp3)-H amination was observed, which may be instructive in the development of an understanding of visible-light-induced triplet nitrene transformation reactions.