36151-19-6

Upstream product

• 90245-62-8 WCl₂(PMePh₂)4 
• 30411-57-5 tetrachlorobis(methyldiphenylphosphine)molybdenum(IV) 
• 144194-56-9 WCl₃(P(CH₃)(C₆H₅)2)3 
• 144299-53-6 ReCl₄(PMePh₂)2 
• 30062-11-4 dichlorotris(methyldiphenylphosphine)oxomolybdenum 
• 13283-01-7 tungsten(VI) chloride 
• 1486-28-8 diphenyl(methyl)phosphine 
• 7647-01-0 hydrogenchloride 
• 36216-85-0 W(O)Cl₂(P(CH₃)(C₆H₅)2)3 

Downstream Products

• 81848-47-7 [WCl₃H(NNHC₆H₅)(PCH₃(C₆H₅)2)2] 
• 36216-85-0 W(O)Cl₂(P(CH₃)(C₆H₅)2)3 

Relevant academic research and scientific papers

A tungsten-mediated closed cycle of reactivity for the reduction of CO 2 to CO

The recycling of CO2 by reduction to CO is an important objective in the context of renewable carbon feedstock chemicals. A tungsten-mediated reduction of CO2 to CO reported by Mayer and coworkers has been re-examined, and it is shown that a series of four well-defined stoichiometric steps can be executed which form a closed cycle and sum as CO2 + 2H+ + 2e- → CO + H 2O. Energetic parameters of this system are probed by cyclic voltammetry, by calculations of gas-phase reaction enthalpies for each of the four steps, and by calculation of the WO bond dissociation energy for the tungsten species that results from oxidation addition of CO2.

Oxygen and chlorine atom transfer between tungsten, molybdenum, and rhenium complexes. Competition between one- and two-electron pathways

Inter-metal oxygen atom transfer reactions between molybdenum, tungsten, and rhenium complexes are described. With only chloride and PMePh2 as supporting ligands, oxygen atom transfer is observed from rhenium to molybdenum and tungsten and from