36231-13-7

Usage

Physical state

Colorless liquid

Odor

Mild, aromatic

Usage

a. Solvent in chemical production
b. Intermediate in the production of synthetic resins and plasticizers
c. Carrier solvent in pesticide formulations
d. Corrosion inhibitor in metalworking fluids
e. Ingredient in fragrance formulations

Flammability

Flammable

Safety precautions

Handle and store with caution

InChI:InChI=1/C10H14/c1-2-6-10-8-4-3-7-9(10)5-1/h1-2H,3-8H2

Upstream product

• 91-20-3 naphthalene 
• 76648-40-3 anti-Tricyclo<4.4.1.0^1,6>undec-3-en-11-ylamin 

Downstream Products

• 67662-24-2 trans-11,12-Diphenyltricyclo<4.4.2.0^1,6>dodeca-3,8-dien 
• 38760-88-2 11,11-Dibromtricyclo<4.4.1.0^1,6>undec-3-en 
• 67662-25-3 9,10-Diphenyl-1,4,5,8-tetrahydro-4a,8a-etheno-naphthalene 
• 134801-46-0 C₂₀H₁₉Cl₂N₃O₂ 
• 880259-84-7 C₁₇H₂₁NO₃S 
• 119-64-2 tetralin 
• 13837-12-2 3,4,5,6,7,8-hexahydro-2(1H)-naphthalenone 
• 70528-30-2 anti-4,4,12,12-tetrabromotetracyclo<5.4.1.0^1,7.0^3,5>dodecane 
• 83692-67-5 anti-11-chlorobicyclo<4.4.1>undeca-1,3-dien-6-ol 
• 83692-66-4 anti-6-chloromethylenecyclodec-3-enone 
• 826-73-3 1-Benzosuberone 
• 83692-65-3 (11R,6S)- and (11S,6R)-11-chlorobicyclo<4.4.1>undeca-1(10),3-dien-6-ol 
• 83692-62-0 anti-11-chloro-1,6-dihydroxybicyclo<4.4.1>undec-3-ene 
• 83692-68-6 cis-bicyclo<4.4.0>dec-3-ene-1-carboxylic acid 

Relevant academic research and scientific papers

(2-Vinylcyclopropyl)carbenes. More stepwise mechanisms for ring-expansion

A simple vinyl group is sufficient to induce a stepwise mechanism for the ring expansion of cyclopropylcarbenes.

A SAFE AND CONVENIENT NEW PROCEDURE FOR REDUCING AROMATIC COMPOUNDS TO BIRCH-TYPE PRODUCTS

Aromatic compounds can be reduced by a calcium-amine-t-butyl alcohol system to products which are identical to those obtained by a Birch reduction of the same substrates.

Nucleophilic Substitution at Tricyclo1,6>undec-3-ene-11-diazonium Ions

The nitrous acid deamination of tricyclo1,6>undec-3-en-11-ylamines 14 and 16 in the presence of sodium bromide afforded the tricyclic bromides 18 and 19 with > 99percent retention.Configurations were assigned by chemical correlation via the carboxylic acids 13 and 15.Deuterium incorporation in D2O indicated some epimerization of the diazonium ions at higher concentrations of sodium bromide, leading to a decrease in stereospecificity.The retention of configuration observed in this study is attributed to the intervention of partially opened cyclopropyl cations.