36237-66-8Relevant articles and documents
A Unified Approach for the Total Synthesis of cyclo-Archaeol, iso-Caldarchaeol, Caldarchaeol, and Mycoketide
Andringa, Ruben L. H.,Driessen, Arnold J. M.,Minnaard, Adriaan J.,de Kok, Niels A. W.
supporting information, p. 17497 - 17503 (2021/06/08)
Ir-catalyzed asymmetric alkene hydrogenation is presented as the strategy par excellence to prepare saturated isoprenoids and mycoketides. This highly stereoselective synthesis approach is combined with an established 13C-NMR method to determine the enantioselectivity of each methyl-branched stereocenter. It is shown that this analysis is fit for purpose and the combination allows the synthesis of the title compounds with a significant increase in efficiency.
Analysis of the labial gland secretion of the cuckoo-bumblebee (Psithyrus vestalis) males and synthesis of abundant geranylcitronellol
Valterova, Irena,Svatos, Ales,Hovorka, Oldrich
, p. 1501 - 1508 (2007/10/03)
Labial glands of the cuckoo-bumblebee males of the species Psithyrus vestalis were extracted and the components of their secretions were identified. Chemical composition of the males' signal of Psithyrus vestalis has not yet been described in the literatu