362598-56-9Relevant articles and documents
A putatively unfeasible Heck reaction - From cyclopentenones to annulated ring systems
Dyker, Gerald,Markwitz, Hardy,Henkel, Gerald
, p. 2415 - 2423 (2007/10/03)
2-Iodocyclopentenones undergo a Heck reaction with allylic and homoallylic alcohols, in acceptable yields, to give dicarbonyl compounds useful for the construction of annulated cyclopentanones. In contrast, the corresponding iodo-substituted cyclohexenones, cycloheptenones and acyclic α,β-unsaturated ketones are far less or even unsuitable for Heck reactions of this type.