362623-91-4Relevant academic research and scientific papers
Spirastrellolide B: The synthesis of southern (C9-C 2S) region
Chandrasekhar, Srivari,Rambabu, Chegondi,Reddy, Annareddy Syamprasad
supporting information; experimental part, p. 4355 - 4357 (2009/06/18)
(Chemical Equation Presented) A combination of chiron and asymmetric approaches is utilized to construct the southern (C 9-C25) region of marine natural product spirastrellolide B. The key functionalities are derived from D-glucose and Sharpless asymmetric epoxidation and dihydroxylation.
An approach towards the C1-C16 fragment of antineoplastic macrolide bryostatins by kinetic resolution of a racemic terminal epoxide using Jacobsen's catalyst
Yadav,Bandyopadhyay,Kunwar
, p. 4907 - 4911 (2007/10/03)
A stereo- and enantioselective approach towards the C1-C16 fragment of bryostatins is reported using Jacobsen's catalyst for kinetic resolution of a terminal epoxide, a Horner-Wadsworth-Emmons coupling reaction and a 1,4-Michael type cyclization as key steps.
