36291-55-1

Basic information

• Product Name: Cyclohexene, 1-methyl-6-nitro-
• CAS NO: 36291-55-1
• Molecular Formula: C7H11NO2
• Molecular Weight: 141.17
• Mol File: 36291-55-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Cyclohexene, 1-methyl-6-nitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexene, 1-methyl-6-nitro-(36291-55-1)
• EPA Substance Registry System: Cyclohexene, 1-methyl-6-nitro-(36291-55-1)

Safety Data

• Hazardous Substances Data: 36291-55-1(Hazardous Substances Data)

Upstream product

• 591-49-1 1-methylcyclohex-1-ene 
• 75-05-8 acetonitrile 

Downstream Products

• 41771-14-6 C₁₃H₁₄ClN₃O₂ 
• 36291-62-0 2-methyl-3-nitrocyclohex-2-enone oxime 
• 1121-18-2 2-methyl-2-cyclohexen-1-one 
• 36601-70-4 2-methyl-1-nitrocyclohex-1-ene 
• 36601-72-6 4-(2'-Methylcyclohex-2'-enoxy)-2-nitrophenol 

Relevant articles and documents

Synthesis and conjugate addition reactions of N-(β-nitroalkyl)amides

Nitration of several di- and trisubstituted alkenes with lithium nitrate/TFAA in nitrile solvents afforded N-(β-nitroalkyl)amides in 28-72% yields. Nitration of 1,1-diphenylethene gave 1,1-diphenyl-2-nitroethene in 52% yield instead of the N-(β-nitroalkyl)amide. Reaction of 1-methylcyclohexene using excess lithium nitrate/TFAA in acetonitrile gave a single diastereomer of N-(2,6-dinitro-1-cyclohexyl)acetamide in 55% yield. N-(β-Nitroalkyl)amides underwent diastereoselective Michael addition to a variety of Michael acceptors. Diastereoselectivity is rationalized on the basis of internal hydrogen-bonding within the intermediate nitronate resulting in a strongly-biased Michael donor conformation.

Acetyl chloride - Silver nitrate - Acetonitrile: A reagent system for the synthesis of 2-nitroglycals and 2-nitro-1-acetamido sugars from glycals

A new reagent system comprising acetyl chloride, silver nitrate, and acetonitrile has been developed for the synthesis of 2-nitroglycals from the corresponding glycals. Under certain conditions, the formation of 2-nitro-1-acetamido sugars has also been observed. In addition, a few other non-carbohydrate-derived olefins also gave the corrresponding conjugated nitroolefins.