36297-89-9

Usage

InChI:InChI=1/C12H8N2O4Se2/c15-13(16)9-1-5-11(6-2-9)19-20-12-7-3-10(4-8-12)14(17)18/h1-8H

Upstream product

• 98196-77-1 N-succinylcysteamine 
• 19188-18-2 p-nitrophenyl selenocyanate 
• 7664-93-9 sulfuric acid 
• 33350-70-8 4-nitro-benzeneseleninic acid 
• 56790-57-9 4-nitrobenzeneselenenyl bromide 
• 7732-18-5 water 
• 103381-41-5 4-nitroselenophenol 
• 97338-68-6 (4-methoxybenzyl)(4-nitrophenyl)selane 
• 24067-17-2 4-nitrophenylboronic acid 
• 586-78-7 para-nitrophenyl bromide 
• 100-01-6 4-nitro-aniline 
• 91208-29-6 tribromo-(4-nitro-phenyl)-λ⁴-selane 
• 7664-41-7 ammonia 
• 100-00-5 4-chlorobenzonitrile 

Downstream Products

• 17417-86-6 allyl(4-nitrophenyl)selane 
• 1290541-94-4 2,5-bis(p-nitrophenylseleno)hydroquinone dimethyl ether 
• 1200317-62-9 (S)-1-(4-nitrophenylselanyl)-3-phenyl-N-tosylpropan-2-amine 
• 69614-78-4 p-nitrophenyl benzyl selenide 
• 53531-56-9 N-Phenylsulfonyl-p-nitrophenylseleniuimidoylchlorid 
• 56790-57-9 4-nitrobenzeneselenenyl bromide 
• 78489-06-2 trichloro-(4-nitro-phenyl)-λ⁴-selane 

Relevant academic research and scientific papers

Green preparation method of aryl diselenium ether type organic selenium compound

The invention discloses an aryl diselenium ether compound synthesis method. The synthesis method comprises the following steps: taking the compound represented by the formula (I) as a reaction raw material, CuBr as a catalyst, KOH in the condition Se, a reducing agent, a disproportionation reaction, water or ethanol as a solvent, and 60 °C. After completion of the reaction, the obtained reaction solution is subjected to post-treatment (if ethanol is recovered as solvent) to obtain the aryl diselenoether compound represented by the formula (II), the yield is close 100%, the subsequent treatment is simple, and a complex separation and purification method is not needed to obtain a pure product. The solvent is recovered as a solvent such as ethanol. , It is preferable. The method is more green. Economy, high efficiency, environmental protection.

Blue light-promoted radical sulfoximido-chalcogenization of aliphatic and aromatic alkenes

A transition metal-free synthesis ofN-(arylthio/seleno)ethyl sulfoxidminesviablue light-promoted radical sulfoximido-chalcogenization of aliphatic and aromatic alkenes was developed. The sulfoximidation process demonstrated high chemoselectivity and allowed a broad substrate scope, completing the sulfoximido-chalcogenization of alkenes in good yields.

Diselenide-Mediated Catalytic Functionalization of Hydrophosphoryl Compounds

We report a diaryldiselenide catalyst for cross-dehydrogenative nucleophilic functionalization of hydrophosphoryl compounds. The proposed organocatalytic cycle closely resembles the mechanism of the Atherton-Todd reaction, with the catalyst serving as a recyclable analogue of the halogenating agent employed in the named reaction. Phosphorus and selenium NMR studies reveal the existence of a P-Se bond intermediate, and structural analyses indicate a stereospecific reaction.

Iodine mediated synthesis of diaryl diselenides using SeO2 as a selenium source

A simple, eco-friendly and convenient procedure has been developed for the synthesis of diphenyl diselinides from readily available aryl boronic acids by reaction with SeO2 in the presence of iodine under simple conditions. The methodology is reported about 19 examples and applicable to a broad scope of aryl boronic acids containing electron-rich and electron-poor substituents. Apart from being milder and environmentally benign conditions, this synthetic protocol comprises a novel, reliable methodology to give good to high yields of the desired diaryl diselenides.

An efficient and practical method for the selective synthesis of sodium diselenide and diorganyl diselenides through selenium reduction

Studies on an efficient and practical method for the selective synthesis of diorganyl diselenides over diorganyl selenides are presented. Considering the discrepancies between reports on organoselenium compounds, we wanted to establish a tolerable synthetic method for diorganyl diselenides and investigate their characteristics. We optimized reaction conditions for sodium diselenide preparation using selenium, NH2NH2·H2O, and NaOH and, by treating the obtained sodium diselenide with various alkyl or aryl halides, achieved the selective synthesis of diorganyl diselenides in modest to good yields (57–88%) with good reproducibility. We further studied the mechanistic implication, the effects of solvent changes, and the stability of diorganyl diselenides.

Rhodium-Catalyzed Carbene Transfer Reactions for Sigmatropic Rearrangement Reactions of Selenium Ylides

The rearrangement of selenium ylides is even today almost unexplored, although it would provide access to important organoselenium compounds with broad downstream applications. In this report, the first systematic study of sigmatropic rearrangement reactions of selenium ylides using a simple rhodium catalyst with catalyst loadings as low as 0.01 mol % is described. Selenium oxide pyrolysis of the rearrangement products gives access to important 1,1-disubstituted butadienes.

CuO nanoparticles-catalyzed a novel method to the synthesis of symmetrical diselenides from aryl halides: selenoamide as an organic Se-donor reagent

A new method is reported for the synthesis of symmetrical diaryldiselenides from aryl halides using selenoamide as an organic Se-donor reagent in the presence of copper (II) oxide nanoparticles. CuO nanoparticles were found to be an efficient and inexpensive catalyst for ligand-free C-Se bond formation with a series of symmetrical diaryldiselenides obtained in good to excellent yield.

The direct synthesis of symmetrical disulfides and diselenides by metal-organic framework MOF-199 as an efficient heterogenous catalyst

A highly crystalline porous copper-based metal-organic framework MOF-199 was synthesized, and characterized by several techniques, including XRD, EDX, SEM, and FT-IR. MOF-199 was used as an efficient catalyst for the one-pot and efficient synthesis of organic dichalcogenides from aryl halides (-OTs) and elemental sulfur and selenium in polyethylene glycols (PEGs). A variety of disulfides and diselenides can be obtained in good to excellent yields of up to 98% in a relatively short reaction time.

Iron-catalyzed formation of C-Se and C-Te bonds through cross coupling of aryl halides with Se(0) and Te(0)/nano-Fe3O4@GO

The formation of C-Se and C-Te bonds is of synthetic and biological importance. Graphene oxide based nano-Fe3O4 (nano-Fe 3O4@GO) is used as a reusable catalyst for the efficient synthesis of diselenides and ditellurides, through cross coupling of Se(0) or Te(0) with aryl iodides. The magnetic heterogeneous catalyst could be easily recovered and reused many times without significant loss of catalytic activity. In addition the superiority of nano-Fe3O4@GO over pristine nano-Fe3O4 is established. Georg Thieme Verlag Stuttgart. New York.

Synthesis of disulfides and diselenides by copper-catalyzed coupling reactions in water

A simple and efficient protocol for copper-catalyzed coupling reactions between aryl halides and elemental sulfur or selenium has been developed. A variety of disulfides and diselenides can be obtained in moderate to excellent yields up to 96%. The Royal Society of Chemistry 2013.