36299-64-6

Usage

Chemical Properties

off-white fine crystalline powder

InChI:InChI=1/C14H16O4/c15-13(16)11-7-6-10(8-12(11)14(17)18)9-4-2-1-3-5-9/h1-5,10-12H,6-8H2,(H,15,16)(H,17,18)/p-2/t10-,11-,12+/m1/s1

Upstream product

• 2305-26-2 cis-1,2,3,6-tetrahydrophthalic acid 
• 71-43-2 benzene 
• 935-79-5 cis-1,2,3,6-tetrahydrophthalic anhydride 
• 2288-18-8 2-phenyl-1,3-butadiene 

Downstream Products

• 336185-24-1 (3aS,5R,7aR)-5-Phenyl-hexahydro-isobenzofuran-1,3-dione 
• 1466-73-5 trans-4-phenylcyclohexanecarboxylic acid 
• 4894-75-1 1-phenyl-4-cyclohexanone 
• 20795-53-3 3-phenylcyclohexanone 
• 107203-07-6 3-Phenylcyclohexanecarboxylic Acid 

Relevant academic research and scientific papers

Practical synthesis of four different pseudoenantiomeric organocatalysts with both cis- and trans-substituted 1,2-cis-cyclohexanediamine structures from a common intermediate

A new and convenient approach has been deviced for the practical synthesis of structurally robust, four different pseudoenantiomeric amino Tf-amido organocatalysts with the unique cis- and trans-substituted 1,2-cis-cyclohexanediamine structures. These pse

Simple and efficient synthesis of new tricarboxylic acids bearing cyclohexane and norbornane fragments

A synthesis new aryl alicyclic tricarboxylic acids bearing two carboxyl groups at either cyclohexane or norbornane fragment and one carboxyl group at the benzene ring was devel-oped. Tricarboxylic acids of this type are promising monomers for the synthesis of hetero-cyclic polymers.

Saturated heterocycle-condensed diphenylisoindolones: Fused-skeleton tetrahydro-1,3-oxazines, oxazolidines and imidazolidines

The addition of benzene to cis-4-cyclohexene-1,2-dicarboxylic anhydride yielded c-2-benzoyl-t-5-phenyl-r-1-cyclohexanecarboxylic acid (72%), or in another reaction, the 4-phenyl isomer (67%). With bifunctional reagents, saturated tricyclic or partially sa

FUSED-SKELETON SATURATED SIX-MEMBERED 1,3-N,O, N,N AND N,S HETEROCYCLES, FUSED-SKELETON ARYL-SUBSTITUTED SATURATED ISOINDOLONES

In the introduction, a brief survey is given of the main types of fused-skeleton saturated six-membered 1,3-heterocycles serving as model compounds in our earlier investigations and as starting compounds in the present studies.The synthesis and conformational analysis of aryl-substituted fused-skeleton saturated 1,3-oxazines and of aryl-substituted hetero-condensed saturated isoindolones are treated. cis-trans isomerization in the saturated isoindolone moiety of the resulting tricyclic, tetracyclic and pentacyclic systems is discussed in connection with the ring-closure reactions of cis- and trans-1,2-disubstituted 1,2- and 1,3-difunctional alicyclic compounds to give alicycle-fused six-membered 1,3-heterocycles.The cycloaddition reactions of dihydro-1,3 and 3,1-oxazines and the conformations of the alicycle-fused tetrahydrooxazine-azetidinone derivatives obtained are presented.Methods are given for the preparation of saturated thiazolo- and thiazinoquinazolinones.Unambiguous, mainly one-pot syntheses for the preparation of 1,3-heterocycles by a retro Diels-Alder method are discussed.