36310-05-1Relevant academic research and scientific papers
Intramolecular aromatic 1,5-hydrogen transfer in preparation of oxacyclic naphthalic anhydride via unusual Pschorr cyclisation
Qian,Cui,Zhang
, p. 2656 - 2657 (2001)
Unusual Pschorr cyclisation via naphthyl radical-induced intramolecular aromatic 1,5-hydrogen transfer using the corresponding diazonium salts as starting materials gave five- and six-membered oxacyclic-fused naphthalic anhydride isomers.
CYANATED BENZOXANTHENE AND BENZOTHIOXANTHENE COMPOUNDS
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, (2016/10/11)
The present invention relates to cyanated compounds of the formula (I) wherein at least one of the radicals R2, R3, R4 and R5 is CN, and the remaining radicals are selected from hydrogen, chlorine and bromine; X
The quest for highly fluorescent chromophores: Evaluation of 1H,3H-isochromeno[6,5,4-mna]xanthene-1,3-dione (CXD)
Al-Aqar, Roza,Avis, Daniel,Benniston, Andrew C.,Harriman, Anthony
, p. 53072 - 53078 (2015/02/18)
Photophysical properties of the strongly fluorescent dye, 1H,3H-isochromeno[6,5,4-mna]xanthene-1,3-dione (CXD), are reported. This highly planar, rigid dye absorbs at around 420 nm, which is ideal for excitation with a blue laser diode, and is extremely stable towards prolonged illumination. Under near-UV excitation, the dye readily sensitises free-radical polymerisation, forming a plastic film with excellent optical transparency. Weakly structured emission is observed with a small Stokes' shift and remains essentially insensitive to changes in solvent polarity. For example, in tetrahydrofuran the fluorescence quantum yield is 0.96 while the excited-singlet state lifetime is 7.4 ns. Quantum chemical calculations provide further insight into the electronic nature of the dye in solution.
Oxo-heterocyclic fused naphthalimides as antitumor agents: Synthesis and biological evaluation
Tan, Shaoying,Yin, Hong,Chen, Zhuo,Qian, Xuhong,Xu, Yufang
, p. 130 - 138 (2013/05/09)
Three series of novel oxo-heterocyclic fused naphthalimide derivatives (8a-8f, 13a-13d, 17a-17d) were prepared. The newly-synthesized compounds, and their thio-heterocyclic fused analogs (1a-1c, 2a-2d, 3a-3c) exhibited potent antiproliferative activity co
Novel aliphatic N-oxide of naphthalimides as fluorescent markers for hypoxic cells in solid tumor
Yin, Hong,Zhu, Weiping,Xu, Yufang,Dai, Min,Qian, Xuhong,Li, Yuanli,Liu, Jianwen
, p. 3030 - 3037 (2011/07/08)
A series of novel aliphatic N-oxide of naphthalimides (A1-A5) were designed and prepared. The N-O group was firstly introduced into the amine side chain tailed to planar naphthalimide chromophore as hypoxic bioreductive marker. Fluorescence image analysis
Novel N-oxide of naphthalimides as prodrug leads against hypoxic solid tumor: Synthesis and biological evaluation
Yin, Hong,Xu, Yufang,Qian, Xuhong,Li, Yuanli,Liu, Jianwen
, p. 2166 - 2170 (2008/02/01)
Novel tertiary amine N-oxides of naphthalimides were designed and synthesized as potential anticancer agents against hypoxic solid tumors. Although their ctDNA-binding affinities and cytotoxic activities against usual tumor cell lines were lower than thos
Synthesis of a novel oxoxanthenoisoquinoline via a palladium-catalysed cross-coupling reaction; as a fluorophore
Prickett, Mark P.,Singh, Gurdial,Vankayalapati, Hariprasad
, p. 2987 - 2990 (2007/10/03)
Suzuki cross-coupling of a bromoaromatic anhydride with 2-methoxyboronic acid afforded a novel oxoxanthenoisoquinoline. Subsequent coupling with 2,3,4,6-tetra-O-acetyl-D-galactose-1,3-diyl phosphate gave a fluorophore. (C) 2000 Elsevier Science Ltd.
Synthesis of benzimidazoxanthenoisoquinolinones,new intermediates and dyes for synthetic-polymer fibres
Beheshtiha, Y. Sh.,Heravi, M. M.,Salehi, F. Amin
, p. 1177 - 1179 (2007/10/03)
The reaction of 4-chloronaphthalene-1,8-dicarboxylic anhydride 3 with 2-nitrophenol in hot DMF and in the presence of copper powder as a catalyst gives 4 which is reduced to 5 with iron powder and glacial acetic acid. Compound 5 is cyclized to 6. Condensa
Benzoxanthene-3,4-dicarboximides and Benzimidazoxanthenoisoquinolinones
Xuhong, Qian,Shengwu, Ren
, p. 528 - 529 (2007/10/02)
Some benzoxanthene-3,4-dicarboximides and benzimidazoxanthenoisoquinolinones are synthesized, and their physical properties and spectral data are determined.
