36359-98-5

Upstream product

• 88-18-6 2-tert-Butylphenol 
• 925-90-6 ethylmagnesium bromide 

Downstream Products

• 111422-37-8 ω,ω,ω-Trifluoro-2-hydroxy-3-tert-butylacetophenone 
• 111422-38-9 (3-tert-Butyl-2-hydroxy-phenyl)-oxo-acetyl chloride 
• 32094-29-4 C₂₇H₃₂O₂ 
• 57138-53-1 C₂₇H₃₂O₂ 
• 111422-39-0 2-tert-butylphenyl benzoate 
• 127354-33-0 ω-Chloro-2-hydroxy-3-tert-butylacetophenone 
• 127354-32-9 2-(tert-butyl)phenyl 2-chloroacetate 
• 40123-27-1 2-tert-Butylphenyl 3-phenylpropanoate 
• 127354-40-9 1-(2-Hydroxy-3-tert-butylphenyl)-3-phenylpropan-1-one 
• 127354-43-2 2-tert-Butylphenyl 3-phenylpropynoate 
• 127354-44-3 1-(2-Hydroxy-3-tert-butylphenyl)-3-phenyl-2-propyn-1-one 
• 84565-90-2 C₂₈H₃₄O₃ 
• 86847-37-2 C₂₄H₃₄O₂ 
• 3245-25-8 2-(tert-butyl)phenyl acetate 

Relevant academic research and scientific papers

Synthetic approach, regio- and stereochemical characterization and differentiation of new potential antioxidant C- and O-arylglycosides

Two series of C- and O-arylglycosides with potential antioxidant properties have been synthesized, characterized and structurally differentiated. Reinvestigation of a synthetic approach has provided better insight into the products obtained and their chemical structures. Regio- and stereochemical characterization and differentiation of each compound have been carried out in solution, in the crystal, and in the gas phase. A comparison between the data obtained in solution and the crystal structures suggests closely related features in the two states. Mass spectrometry proved very effective for characterization of and differentiation between C- and O-isomers, as well as positional isomers. Unimolecular reactions occurring in the gas phase are specific to the chemical structures, and ion abundances can be related to their stabilities. This study has allowed the evaluation of the influences of the different linkages between the two moieties and the positions of the substituents on the chemical properties of the compounds. The C-isomers show antioxidant capability, as peroxyl radical scavengers, and inhibit lipid peroxidation. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.

METAL TEMPLATE ORTHO-ACYLATION OF PHENOLS; A NEW GENERAL APPROACH TO ANTHRACYCLINONES

Direct and mild synthesis of dihydroxyanthraquinones including 4-demethoxy-7-deoxydaunomycinone 8 from ortho-phthaloyl dichloride and hydroquinone derivatives is described.