3643-41-2Relevant academic research and scientific papers
PALLADIUM DICHLORIDE CATALYZED COPE REARRANGEMENT OF FUNCTIONALIZED ACYCLIC 1,5-DIENES
Overman, Larry E.,Renaldo, Alfred F.
, p. 3757 - 3760 (1983)
The cope rearrangement of acyclic 1,5-dienes having an electronwithdrawing group at carbon-3 and an alkyl substituent at carbon-2 is effectively catalyzed by palladium dichloride.This reaction can be employed to achieve clean γ-allylation of vinyl esters and acids.
