Tetrahedron Letters p. 3757 - 3760 (1983)
Update date:2022-08-04
Topics:
Overman, Larry E.
Renaldo, Alfred F.
The cope rearrangement of acyclic 1,5-dienes having an electronwithdrawing group at carbon-3 and an alkyl substituent at carbon-2 is effectively catalyzed by palladium dichloride.This reaction can be employed to achieve clean γ-allylation of vinyl esters and acids.
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