364336-13-0

Basic information

• Product Name: Benzene, 1,4-dibromo-2-(dodecyloxy)-5-(phenylmethoxy)-
• CAS NO: 364336-13-0
• Molecular Formula: C25H34Br2O2
• Molecular Weight: 526.352
• Mol File: 364336-13-0.mol

Chemical Properties

• CAS DataBase Reference: Benzene, 1,4-dibromo-2-(dodecyloxy)-5-(phenylmethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,4-dibromo-2-(dodecyloxy)-5-(phenylmethoxy)-(364336-13-0)
• EPA Substance Registry System: Benzene, 1,4-dibromo-2-(dodecyloxy)-5-(phenylmethoxy)-(364336-13-0)

Safety Data

• Hazardous Substances Data: 364336-13-0(Hazardous Substances Data)

Upstream product

• 364336-10-7 2,5-dibromo-4-dodecyloxyphenol 
• 100-39-0 benzyl bromide 
• 14753-51-6 2,5-dibromohydroquinone 
• 123-31-9 hydroquinone 

Downstream Products

• 340135-80-0 1-benzyloxy-4-dodecyloxyphenyl-2,5-bis(boronic acid) 

Relevant articles and documents

Chromophore and Polymer Capable of Detecting the Presence of Various Neurotoxins and Method of Use

Applicants have produced a chromophore and a polymer that are highly sensitive to the presence of various agents, including organophosphates, pesticides, neurotoxins, metal ions, some explosives, and biological toxins. The detection is accomplished by detecting a change in the fluorescence characteristics of the chromophore or polymer when in the presence of the agent to be detected. The chromophore and polymer may be incorporated into sensors of various types, and they are adaptable for potential field use in areas where detection of these types of agents is desired.

Intramolecular hydrogen-bond-assisted planarization of asymmetrically functionalized alternating phenylene-pyridinylene copolymers

We report on the synthesis and characterization of a series of asymmetrically functionalized amphiphilic polymers with alternating π-donor units (e.g., substituted benzene) and π-acceptor units (e.g., pyridine) along the polymer backbone. The purpose of our present work involves incorporation of functional groups along the main chain to form intrachain hydrogen bonds, which promote planarization of the polymer backbone, and to fine-tune the optical properties. The structure-property relationship of polymers P1-P6 was investigated by means of analytical methods, such as FTIR spectroscopy, 1H and 13C NMR spectroscopy, UV/Vis spectroscopy, fluorescence spectroscopy, gel permeation chromatography, thermogravimetric analysis, cyclic voltammetry, and X-ray powder diffraction. All polymers were soluble in common organic solvents, and the optical and fluorescence spectra of the polymers showed significant changes according to the formation (P4, P5) or absence (P6) of intramolecular hydrogen bonding along the polymer backbone. Moreover, the 2,6-or 3,5-linkage of the pyridine rings in P5 and P6, respectively, reduced the conjugation along the polymer backbone and this is reflected in their optical properties. The optical properties of the polymers were influenced by the addition of acid (P1-P6), base (P4-P6), and metal ions (e.g., Cu2+, Fe3+, Ag+, Ni2+, Pd2+, Mn2+, Zn2+, Mg2+, and Pr 3+). Such polymers could be used in various applications, including sensors and stimuli-responsive displays.