364359-18-2Relevant academic research and scientific papers
Preparation and reactions of functionalized arylmagnesium reagents
Jensen, Anne Eeg,Dohle, Wolfgang,Sapountzis, Ioannis,Lindsay, David M.,Vu, Viet Anh,Knochel, Paul
, p. 565 - 569 (2002)
Functionalized magnesium reagents have been prepared via an iodine-magnesium exchange. These reagents can be either trapped directly with aldehydes or transmetallated to copper or zinc to participate in cross-coupling reactions. The iodine-magnesium exchange, represent a unique method for the preparation of aryl and heteroaryl magnesium reagents.
Copper-mediated cross-coupling of functionalized arylmagnesium reagents with functionalized alkyl and benzylic halides
Dohle, Wolfgang,Lindsay, David M.,Knochel, Paul
, p. 2871 - 2873 (2007/10/03)
(equation presented) Functionalized arylmagnesium halides, prepared via an iodine-magnesium exchange, undergo a smooth cross-coupling reaction with functionalized primary alkyl iodides and benzylic bromides in the presence of CuCN·2LiCl, either in stoichi
