36459-52-6

Basic information

• Product Name: 4-methoxyphenyl methylphosphonyl chloride
• Synonyms: 4-methoxyphenyl methylphosphonyl chloride
• CAS NO: 36459-52-6
• Molecular Weight: 220.592
• Mol File: 36459-52-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-methoxyphenyl methylphosphonyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methoxyphenyl methylphosphonyl chloride(36459-52-6)
• EPA Substance Registry System: 4-methoxyphenyl methylphosphonyl chloride(36459-52-6)

Safety Data

• Hazardous Substances Data: 36459-52-6(Hazardous Substances Data)

Upstream product

• 676-97-1 methylphosphonic acid dichloroanhydride 
• 150-76-5 4-methoxy-phenol 

Downstream Products

• 154197-00-9 3-cyano-4'-methoxybiphenyl 
• 154196-96-0 4-cyanophenyl 4-methoxyphenyl methylphosphonate 

Relevant articles and documents

Electrophilic Catalysis in the Synthesis of Aryl Methyl- and Phenylphosphonochloridates

The reaction of methyl- and phenylphosphonic dichlorides with phenols in the presence of anhydrous magnesium chloride as catalyst or magnesium metal as precatalyst provides a simple, efficient, and practical method of synthesis of the corresponding aryl m

Photolysis of 4-Methoxyphenyl Aryl Alkylphosphonates

UV irradiation of bis(4-methoxyphenyl) methylphosphonate 1a in methanol gave 4,4'-dimethoxybiphenyl 2a as the main product through an intramolecular excimer.With 4-cyanophenyl-4-methoxyphenyl methylphosphonate 1b 4-cyano-4'-methoxybiphenyl 2c and 4-cyano-2-(4'-methoxyphenyl)phenyl methylphosphonate 4b were obtained through an intramolecular exciplex. 3-Cyanophenyl-4-methoxyphenyl methyl phosphonate 1c gave only 3-cyano-4'-methoxybiphenyl 2f.Methyl 4-methoxyphenyl 4-chlorobenzylphosphonate 5a gave dimethyl 4-chlorobenzyl 2-(4'-methoxyphenyl)phosphonate and dimethyl 2-(4'-methoxyphenyl)benzylphosphonate.