36471-09-7

Basic information

• Product Name: (-)-(S)-(dimethylamino)phenyl(trans-2-phenylethenyl)oxosulfonium fluoroborate
• CAS NO: 36471-09-7
• Molecular Weight: 359.196
• Mol File: 36471-09-7.mol

Chemical Properties

• CAS DataBase Reference: (-)-(S)-(dimethylamino)phenyl(trans-2-phenylethenyl)oxosulfonium fluoroborate(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-(S)-(dimethylamino)phenyl(trans-2-phenylethenyl)oxosulfonium fluoroborate(36471-09-7)
• EPA Substance Registry System: (-)-(S)-(dimethylamino)phenyl(trans-2-phenylethenyl)oxosulfonium fluoroborate(36471-09-7)

Safety Data

• Hazardous Substances Data: 36471-09-7(Hazardous Substances Data)

Upstream product

• 420-37-1 trimethoxonium tetrafluoroborate 

Downstream Products

• 5635-42-7 (3S,4R)-3,4-diphenyldihydrofuran-2(3H)-one 
• 133908-45-9 cis-α,β-Diphenyl-butyrolacton 
• 5635-42-7 C₁₆H₁₄O₂ 

Relevant articles and documents

Asymmetric Synthesis of γ-Lactones through Koga Amine-Controlled Addition of Enediolates to α,β-Unsaturated Sulfoxonium Salts

A chiral Koga amine-controlled asymmetric synthesis of cis-γ-lactones through a formal [3 + 2] cycloaddition of enediolates with α,β-unsaturated sulfoxonium salts is described. The desired structural motif was formed in moderate to good yields (50-71% for 13 examples), with good to very good diastereoselectivity (dr 5:1 to 10:1 for 20 examples), favoring the cis-isomer, and good to excellent enantioselectivity (70-91% ee for 13 examples).